Phthalimide-N-oxyl (PINO) radical, a powerful catalytic agent: Its generation and versatility towards various organic substrates. Catalysis Reviews, 51, 218-292.Coseri, S. (2009a). Phthalimide-N-oxyl (PINO) radical, a powerful catalytic agent: Its generation and versatility towards various ...
The oxidation of a series of alkyl aryl sulfides promoted by the phthalimide N-oxyl radical (PINO) has been investigated by kinetic and product analysis. Sulfoxides are formed as major reaction products in the oxidation of thioanisoles and benzyl phenyl sulfides. The observation of fragmentation pr...
Kinetic study of the phthalimide N-Oxyl (PINO) radical in acetic acid. Hydrogen abstraction from C-H bonds and evaluation of O-H bond dissociation energy of N-hydroxyphthalimide [ J ]. J Phys Chem A ,2003,107 (21) :4262 - 4267.
The generation of the phthalimide-N-oxyl (PINO) radicals from its precursor NHPI, can be achieved by using different ways including electrochemical, enzymatic and chemical methods. Among all of these methods, the use of lead tetraacetate for the PINO radicals' generation seems to be the most ...
In this paper, we report the comparative investigation of reactivity of phthalimide- N -oxyl (PINO) and benzotriazole- N -oxyl (BTNO) radicals toward double bonds of vinyl compounds. The rate constants for radical addition ( k add ) to alkenes were determined experimentally. It has been ...
N-hydroxyphthalimideoxidationsulfideselectron transferradicalThe oxidation of a series of alkyl aryl sulfides promoted by the phthalimide N -oxyl radical (PINO) has been investigated by kinetic and product analysis. Sulfoxides are formed as major reaction products in the oxidation of thioanisoles and ...
Irradiation of N-triphenylmethyloxy- or N-diphenylmethyloxy phthalimide is reported to result in the formation of phthalimide N-oxyl radical (PINO), which is able to initiate and propagate oxidative radical chain reactions of hydrocarbons.doi:10.1016/j.tetlet.2007.05.162Marco Lucarini...
A kinetic study of the electron-transfer reaction of the phthalimide-N-oxyl radical (PINO) with ferrocenes. Baciocchi, Enrico,Bietti, Massimo,Di Fusco, Massimo,Lanzalunga, Osvaldo. Journal of Organic Chemistry . 2007Enrico Baciocchi,Massimo Bietti,Massimo Di Fusco. A Kinetic Study of the ...
Kinetics Electron-Transfer Rxn of the Phthalimide-N-oxyl Radical PINO w FerroceneBaciocchi, EBietti, MDi Fusco, MLanzalunga, O
Thus, in the presence of CAN, NHPI generates the phthalimide-N-oxyl (PINO) radical, which abstracts a hydrogen atom from the benzyl position to form a C-centered radical. The target oxidative cross-coupling product is formed mainly through the recombination of PINO with the C-centered radical...