qualitative energy-level diagrams/ A8250 Photochemistry and radiation chemistry A3190 Other topics in the theory of atoms and moleculesThe mechanism of the photochemical reactions of transition-metal hydrides and dihydrogen complexes is discussed on the basis of recently published potential-energy curves ...
Binuclear platinum(Ⅱ) photochemistry. Reactions of organometallic hydrides with electronically excited tetrakis(pyrophosphito)diplatinate(Ⅱ). Vlcek A,Gray H B. Inorganic Chemistry . 1987VL?EK A, JR,,GRAY H B.Binuclear platinum(II) photochemistry. Reactions of organometallic hydrides with ...
The transient photochemistry in solution and low-temperature matrix photochemistry of Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) are reported; this compound is uniquely effective among first-row transition metal complexes in its ability to activate C-H bonds. Pulsed laser photolysis (308 nm) of alkane...
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The first species observed in laser flash photolysis of the rhenium complex in saturated hydrocarbons has been assigned as an heptacoordinated 16-electron complex, ReH5P2, which is found to react with P at the diffusion-controlled rate. However, for photolysis in benzene such species is replaced...
Presents information on the photolysis of a benzene solution and the benefits of studying the transition of metal hydrides. Outline of the experimental section; Details on results in specific areas; Discussions on findings.FerrariArlenPoloEleonora...
Physical chemistry Ultraviolet photochemistry of the group-V hydrides UNIVERSITY OF SOUTHERN CALIFORNIA Curt Wittig Smith-FreemanLee-Ann MThis dissertation discusses the molecular properties and ultraviolet photochemistry of the group-V hydrides (NH, PH, AsH, SbH, BiH). Relativistic effects become ...
However, in contrast to other transition metal hydrides and methyl substituted (HMn(CO)5, HCo(CO)4, and CH3Co(CO)4Leticia GonzálezInstitut für Chemie und BiochemieChantal DanielInstitut für Chemie und BiochemieJournal of Computational Chemistry...
This dissertation discusses the molecular properties and ultraviolet photochemistry of the group-V hydrides (NH3, PH 3, AsH3, SbH3, BiH3). Relativistic effects become increasingly important for the heavier group-V hydrides and can be manifest in studies of the photodissociation dynamics.;High-n ...
Photochemistry in Hg doped matrices. Infrared spectra of mercury hydrides: HgH2, HgD2, HHgD, HgDExperimental/ associationdeuteriumFourier transform spectrahydrogenhydrogen neutral moleculesinfrared spectra of polyatomic inorganic moleculesinorganic molecule configurations...