▶ PdCl2(phen)/KI was successfully employed in the reaction for the first time. ▶ I− and phen complexes used in the reaction show synergistic effect on the activity. ▶ Oxidative carbonylation of glycerol present a new platform to valorize glycerol....
time a quaternary NiCl2–FeCl3–PdCl2–GIC of which intercalates due to chemical exfoliation are transformed to nanoclusters highly dispersed in expanded graphite matrix followed by further reduction to metallic particles during the cathodic process of hydrogen sorption occurring in 6 M KOH solution....