This suggests the possibility that (i) reactions of Meox with Li2PdCl4 may lead directly to the trans-form of [PdCl2(Meox)(2)] or alternatively (ii) that alkyloxazoline complexes such as 4 may have a different, and presumably much more rapid, mechanism for isomerisation. The results are...
Phosphitooxazoline [Rh(CO)2Cl]2 ligand for allylalcetate Pd cat asymm allylic π-allyl sulfinate sulfonylationBondarev, O G
The complexes reported herein represent the first transition metal derivatives of these high molecular weight, long chain and presumably low polarity monodentate oxazoline ligands. A combination of spectral and theoretical calculations (semi-empirical PM 6(tm) level of theory) are used to support the ...
Direct ortho-palladation of sterically non-hindered 2-phenyl-2-oxazoline (1) using Pd(OAc)2 and AcONa in AcOH provided di-μ-acetatobis-[2-(2-oxazolinyl)phenyl,1-C,3-N]dipalladium(II) (3a) in a yield of 63%. Dimeric complex 3a was converted into the corresponding μ-chloro analog ...