This work describes a mild and efficient approach for the synthesis of aryl amides via catalytic aminocarbonylation of aryl halides with alicyclic amines using a Pd(PtBu3)2/NH4Cl catalyst system. Under...doi:10.1002/aoc.3637John Wiley & Sons, LtdApplied Organometallic Chemistry...
The reaction of Pd(PtBu3)2 with the strong acids H3O+X−, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-[(tBu3P)2Pd(H)(H2O)]X. The thermally stable hydrides trans-[(tBu3P)2Pd(H) (CH3CN)]X were obtained by substitution of the water molecule by CH3CN. The re...
The reactivity of Pd(PtBu3)2 towards the oxonium ion. Crystal structure of trans-[(tBu3P)2 Pd(H)(CH3CN)]BPh4 The reaction of the aquo-hydrides with CO, yielding [Pd(CO)(PtBu3)]2 and the crystal structure of trans[[(tBu3P)2Pd(H) (CH3CN)]BPh4 are ... SD Braga - 《Journa...
[Pd(μ-Br)(PtBu3)]2 as a Highly Active Isomerization Catalyst: Synthesis of Enol Esters from Allylic Esters The dimeric Pd(I)-complex [Pd(μ-Br)(PtBu3)]2 was found to be highly active for catalyzing double-bond migration in various substrates such as unsaturated ... P Mamone,MF Grünb...
The clusters already reported as [{Pt(diphos)(RNC)}2Pt](PF6)2, (diphos = cis-Ph2PCHCHPPh2, Ph2P(CH2)3PPh2, or tBu2P(CH2)2PtBu2; R = 2,6-xylyl or 2,4,6-mesi... † Tomoaki Tanase,,†A Yasuhiro Yamamoto,RJ Puddephatt‡ - 《Organometallics》 被引量: 87发表: 1996...
1621274-11-0 PtBu3 Pd G4 价格电议 起批量≥1 最小起订1 供货总量1000 发货地址湖北省武汉市 建议售价￥1 更新日期2024年12月03日 产品规格1kg 即时洽谈立即询价查看联系方式 收藏产品发送留言 VIP3年 湖北汉威化工有限公司 企业认证:备 营业执照和法人身份证已备案 ...
The reactivity of Pd(PtBu3)2 towards the oxonium ion : Crystal structure of trans-[(tBu3P)2Pd(H)(CH3CN)]BPh4; ; ; ; ; Dip. chimica chimica industriale, Pisa 56126, ITALIE聽聽聽聽聽聽JORCAI聽 1991,聽vol.聽418,聽n1,聽pp.聽119-126聽(24 ref.)AnglaisElsevier, Lausanne, SUISSE聽 (...
A concurrent reaction pathway involving simultaneous oxidative addition of chloroarenes to [Pd(PtBu3)] and [(PtBu3)Pd(OR)]- may explain the dependence of the rates of reactions of electron-rich and electron-neutral chloroarenes on the identity and concentration of bases. The rates of reactions...
Troadec T, Tan S-Y, Wedge CJ, Rourke JP, Unwin RR, Chaplin AB (2016) One-electron oxidation of [M(PtBu3)2] (M = Pd, Pt): isolation of monomeric [Pd(PtBu3)2]? and redox-promoted C-H bond cyclometalation. Angew Chem Int Ed 55:3754-3757...
Hu, Q S