(Br)] 2 by substituting two triphenylphosphine ligands.In dichloromethane complex 2 at room temperature for 8 h,it undergoes displacement of the triphenylphosphine ligand to form the dipalladium complex [Pd(PPh3)Br]2(mu,eta~2-CSCHCHN)2 3 in which the two thiazoline ligands coordinated through ...
[Hg(mtsZ)2(dppb)](4), [Hg(mtsZ)2(dppf)](5), [Hg(mtsZ)2(PPh3)2](6), [Hg(mtsZ)2(Bipy)](7), [Hg(mtsZ)2(Phen)](8), from 1-2-meracpto-5-methyl-1,3,4-thiazdiazole (HmtzS) and phosphines or diamines, and study the ability of the complex (1) to hydrogen ...
Double NˆCˆC cyclometalation with dianionic NˆCˆC2− ligands based on diphenyl-2-pyridine (Hdphpy) was never observed for Pt(II), while for Pd(II) and Ni(II), the complexes [M(dphpy)(PPh3)] (M = Pd and Ni) were recently reported [56]. In contrast to this, −...
Influence of the dba substitution on the reactivity of Palladium(0) complexes generated from Pd02(dba-n,n'-Z)3 or Pd0(dba-n,n'-Z)2 and PPh3 in oxidative addition with iodobenzene. Organometallics 2006, 25, 1795–1800. 32. Köcher, S.; Walfort, B.; Mills, A.M.; Spek, A.L.;...