PEPPSIA robust, mild, and efficient method for the Pd-catalyzed N-heteroarylation of optically pure 伪-amino esters was developed. Dichloro[1,3-bis(2,6-di-3-pentylphenyl)imidazol-2-ylidene]( o -picoline)palladium(II) (Pd-PEPPSI-IPentCl- o -picoline; PEPPSI=pyridine enhanced pre-catalyst ...
The new catalyst described herein, Pd-PEPPSI-IPentCl-o-picoline, is able to aminate profoundly deactivated coupling partners when using only carbonate base at room temperature.doi:10.1002/ange.201310457MatthewPompeoJenniferL.FarmerRobertD.J.Froese...
The new catalyst described herein, Pd‐PEPPSI‐IPentCl‐o‐picoline, is able to aminate profoundly deactivated coupling partners when using only carbonate base at room temperature.doi:10.1002/anie.201310457Matthew PompeoDepartment of Chemistry, York University, 4700 Keele Street, Toronto, ON, M3J 1...
ChemInform Abstract: Room-Temperature Amination of Deactivated Aniline and Aryl Halide Partners with Carbonate Base Using a Pd-PEPPSI-IPentCl-o-Picoline Catalystdoi:10.1002/chin.201436079amines (benzene compounds)amination, N-alkylation, N-arylation...
The new catalyst described herein, Pd-PEPPSI-IPentCl-o-picoline, is able to aminate profoundly deactivated coupling partners when using only carbonate base at room temperature.doi:10.1002/anie.201310457Matthew PompeoDepartment of Chemistry, York University, 4700 Keele Street, Toronto, ON, M3J 1P3 ...
The new catalyst described herein, Pd-PEPPSI-IPentCl-o-picoline, is able to aminate profoundly deactivated coupling partners when using only carbonate base at room temperature.doi:10.1002/ange.201310457Matthew PompeoDepartment of Chemistry, York University, 4700 Keele Street, Toronto, ON, M3J 1P3 ...