Mizoroki-Heck反应、Suzuki-Miyaura偶联等常见的C-N、C-C键偶联中提及实验安全的工作整理汇总,撰写了题为Potential Safety Hazards Associated with Pd-Catalyzed Cross-Coupling Reactions的文章,相关内容发表在化学期刊Org. Process Res. Dev.上。
论文信息: Pd(II)-Catalyzed C(alkenyl)–H Activation Facilitated by a Transient Directing Group Mingyu Liu, Juntao Sun, Tuğçe G. Erbay, Hui-Qi Ni, Raúl Martín-Montero, Peng Liu*, Keary M. Engle* Angew. Chem. Int. Ed. DOI: 10.1002/anie.202203624 CBG资讯一直致力于追踪新鲜科研资讯、...
论文信息 Catalytic Asymmetric Cascade Dearomatization of Indoles via a Photoinduced Pd-Catalyzed 1,2-Bisfunctionalization of Butadienes Xiaohang Zhan, Zhiwen Nie, Na Li, Ao Zhou, Haotian Lv, Mingrong Liang, Keqin Wu, Guijuan Cheng, Qin Yin https://doi.org/10.1002/anie.202404388 殷勤团队因工作...
Pd-Catalyzed Asymmetric β-Hydride Elimination En Route to Chiral Allenes Wewish to report our preliminary results on the discovery anddevelopment of a catalytic, asymmetric 尾-hydride eliminationfrom vinyl Pd(II)-complexes derived from enol triflates to accesschiral allenes. To achieve this, we ...
A Pd-catalyzed oxidative C–H amination of N-Ts-2-arylanilines under ambient temperature using Oxone as an inexpensive, safe, and easy-to-handle oxidant has been developed. This process represents a green and practical method for the facile construction of carbazoles with a broad substrate scope...
The use of alkyl chlorides in Pd-catalyzed Mizoroki–Heck coupling reactions remains an unsolved problem despite their significant potential for synthetic utility and applicability. The combination of the high thermodynamic barrier of alkyl chloride activation and kinetic propensity of alkylpalladium complexes...
Synthesis of Chiral Aldehyde Atroposelective C−H NaphthylCaatitoanly sts via Pd-Catalyzed” Liao, G.; Chen, H.-M.; Xia, Y.-N.; Li, B.; Yao, Q.-J.; Shi, B.-F.* Angew. Chem. Int. Ed.2019, Just Accepted Manu DOI: 10.1002/anie.201906700 ...
Scheme 4. Pd(0)-Catalyzed Difunctionalization of 1,3-Enynes 4、Pd(0)-π-Lewis碱HOMO活化缺电1,3-二烯 4.1Pd(0)活化直链缺电1,3-二烯 不同于电中性1,3-二烯,缺电1,3-二烯通常作为Michael受体与亲核试剂发生1,4-或1,6-共轭加成反应。尽管σ-Lewis碱和Ni(0)可被用于催化缺电1,3-二烯与亚胺...
Scheme 4. Pd(0)-Catalyzed Difunctionalization of 1,3-Enynes 4 Pd(0)-π-Lewis碱HOMO活化缺电1,3-二烯 4.1 Pd(0)活化直链缺电1,3-二烯 不同于电中性1,3-二烯,缺电1,3-二烯通常作为Michael受体与亲核试剂发生1,4-或1,6-共轭加成反应。尽管σ-Lewis碱和Ni(0)可被用于催化缺电1,3-二烯与亚...
Pd-Catalyzed microwave-assisted synthesis of phosphonated 13α-estrones as potential OATP2B1, 17β-HSD1 and/or STS inhibitors Pd-Catalyzed microwave-assisted synthesis of phosphonated 13α-estrones as potential OATP2B1, 17β-HSD1 and/or STS inhibitors... R Jójárt,S Pécsy,G Keglevich,....