Treatment of N-heterocyclic silylene Si[N(tBu)CH]2 ( 1 ) and [(3-C3H5)PdCl]2 in toluene led to the formation of the mononuclear complex (3-C3H5)Pd{Si[N(tBu)CH]2}Cl ( 3 ), the silicon analogue to N-heterocyclic carbene complex (3-C3H5)Pd{C[N(tBu)CH]2}Cl ( 2 ). ...
Reactions of [(eta5-C5H5)Ru(PR'3)2(Cl)] with NaBAr(F) [BAr(F)-=B{3,5-[C6H3(CF3)2]}4-; PR'3=PEt3 or 1/2Et2PCH2CH2PEt2) (depe)] and PR2H (R=Ph, a; tBu, b; Cy... JG Planas,F Hampel,JA Gladysz - 《Chemistry》 被引量: 75发表: 2005年 Efficient Synthesis of...
Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(eta3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% i... R Kuwano,M Yokogi - 《Chemical Communication...
η3-C3H51 or Cl(PPh3) 2} which, in the presence of Me3NO, react with [NBun4]I, [NBun4]Br, [PPN]Cl or [NBun4]NCS to give [(OC)XRh(-p-MeC6H4NNNC6H4Me-p)2PdCl(PPh3)] (X = I 3, Br 4, Cl 5 or NCS 6) and [NBun4][(OC)XRh(-p-MeC6H4NNNC6H4Me-p)2Pd(η...
X-RAYDIASTEREOSELECTIVITYA complex generated in situ from [Pd(eta(3)-C3H5)Cl](2) and (S)-BINPO 1 is an active catalyst in the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl esters 6 via a malonate anion with ee's LIP to 81% being obtained. Rate and stereoselectivity of ...
ChemInform Abstract: Preparation of (Me3P)2Pd2(.mu±eta.3‐C3H5)(μ‐SPh) by Reaction of Pd(0) Complex with Allyl Phenyl Sulfide.organo‐palladium compoundsstructure (organic substances)ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about ...
et al., " Synthesis and structures of the transition metal(II) beta-diketiminates [ML2] (M=Mn, Fe, Ni, Cu, Pd), [ML'2[ (M=Ni, Cu) and [M(eta3-C3H5)L] (M=Ni, Pd); L or L'=[{N(SiMe3 or H)C(Ph)]2CH], " Journal of Organometallic Chemistry, 2009, vol. 694, ...
ChemInform Abstract: Preparation of (Me3P)2Pd2(.mu±eta.3‐C3H5)(μ‐SPh) by Reaction of Pd(0) Complex with Allyl Phenyl Sulfide.organo‐palladium compoundsstructure (organic substances)ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from...
The complexes [(η3-C6H9)Pd(η2-S2CNR2)] (R=Me, 1; Et, 2), [(η3-Me2CCMeCH2)Pd (η2-S2COEt)] 3 and [(η3-Me2CCMeCH2)Pd(η2-S2PPh2)] 4 have been synthesized by reaction of [(η3-allyl)Pd(μ-Cl)]2 with NaS2CNR2 (R=Me, Et), KS2COEt and NaS2PPh2. The...
et al., " Synthesis and structures of the transition metal(II) beta-diketiminates [ML2] (M=Mn, Fe, Ni, Cu, Pd), [ML'2[ (M=Ni, Cu) and [M(eta3-C3H5)L] (M=Ni, Pd); L or L'=[{N(SiMe3 or H)C(Ph)]2CH], " Journal of Organometallic Chemistry, 2009, vol. 694, ...