(OBu)4;reactive—polymerization塑料作为近代化学工业领域最重要的发明.之一,已经广泛应用于工业、农业、医疗卫生、商业贸易等各个领域.然而,废旧塑料所造成的“白色污染”正日益严重地危害着生态环境,阻碍了社会的进步和经济的可持续发展.目前,如何把“白色污染”降到最低点,保证国民经济持续发展,实现经济、资源、环境...
冷却至RT后,支架被固定到被从缺陷保留在除去其新的临时形状。 一个SMP支架材料的形状记忆行为由应变控制环状热机械压缩试验在形状固定性(Rf)和形状恢复(RR)(图3)来表示定量。对于这个PCL基SMP支架,值(%)为周期N = 1和2是,RF(1)=102.5 0.7,RF(2)=101.80.3,RR(1)95.3 0.9,和RR (2)= 99.8 0.26。 在...
In-situ polymerizationRecently, Graphene oxide (GO) has attracted enormous interests due to its extraordinary properties. GO sheets are expected to find a variety of applications, such as GO-based composites materials and biotechnology. The nanocomposites of Poly (蔚-caprolactone) (PCL) and graphene...
In the condition of using metal organic compounds(tetraphenyl tin) as the catalyst,with polymercontain two or three hydroxyl as the initator,Polycaprolanctone is ring opening polymerization from caprolactone monomer 产品优点 Product Advantages 高结晶性和低熔点性,可低温成型 在难粘基材上具有优异...
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Key words:PCL-PEG-PCL isothermal crystallization; ε-caprolactone ; ethylene glycol ; ring-opening polymerization 目录 序言1 1.1两亲性嵌段共聚物胶束1 1.2内酯(含交酯)2 1.3聚己内酯(PCL)3 1.3.1 PCL的生物相容性3 1.3.2 PCL良好的渗透性和形状记忆特性3 1.4聚乙二醇(PEG)4 第一章实验原料和仪器5 1.1...
(diethylamino)ethyl methacrylate)-b-poly(poly(ethylene glycol) methyl ether methacrylate)]2 [(PCL)2(PDEA-b-PPEGMA)2] were developed by a combination of ring opening polymerization (ROP) and continuous activators regenerated by electron transfer atom transfer radical polymerization 30 35 (ARGET ...
pcl及mpegpcl嵌段共聚物微球的研究
Chlorodiphenylphosphine (CDP) was used as a pre-initiator in the polymerization of methacrylates having methyl, benzyl,-butyl,-butyl, cyclohexyl, and-hexyl substituents in the presence of catalytic amounts of epoxides. This polymerization system was influenced by solvents and epoxides structure, and ...
硕士论文--PCL及mPEG-PCL嵌段共聚物微球的研究 上海交通大学 硕士学位论文 PCL及mPEG-PCL嵌段共聚物微球的研究 姓名:刘丽波 申请学位级别:硕士 专业:药剂学 指导教师:郭圣荣 20090101