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The compound thus formed may be used as a catalyst in the preparation of copolymers of carbon monoxide with at least one ethylenically unsaturated compound (preferably an α-olefin having 2 to 8 carbon atoms, and especially ethylene); the copolymerization is preferably carried out at a pressure...
Trichloroethylene Hydrodechlorination in Water Using Formic Acid as Hydrogen Source: Selection of Catalyst and Operation Conditions This work studies the aqueous-phase hydrodechlorination of trichloroethylene (TCE), using formic acid (FA) as hydrogen source, over different Pd-based cata... E Díaz,A Mc...
An efficient method was developed for the direct acylation of arene sp2 C−H bonds with alcohols using palladium chloride as a catalyst and peroxide as the oxidant. The alcohols were oxidized to their corresponding aldehydes in situ and efficiently coupled with 2-arylpyridines to give aryl ketone...
摘要: A terpyridine-based organic-inorganic hybrid molecule was synthesized, and itself-assembled nanostructure with palladium was characterized. The catalyst activity of the nanofibers was examined in the Sonogashira coupling and the Heck reactions at reflux temperature....
A new synthesis of a polycinnamamide using palladiumゞraphite as a catalyst for carbonヽarbon bond formation 来自 国家科技图书文献中心 喜欢 0 阅读量: 14 作者:M Jikei,M Miyauchi,Y Ishida,MA Kakimoto,Y Imai 摘要: First page of article ...
Kaili Catalyst New Materials CO., LTD is a holding subsidy of Shaanxi Rare Metal Science & Engineering Group (former Northwest Institute for Nonferrous Metal Research). It brings together R&D, production and evaluation experts and equipment keeping up wi
PROBLEM TO BE SOLVED: To provide a catalyst highly active and highly selective even at low working temperature by depositing a prescribed thickness and amount of palladium as a sol on a carrier by impregnation or successive spraying and heating processes. SOLUTION: A palladium sol is previously ...
Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation. Uses Application Guide for...
Thus, the coupling of a t-butyl cyclobutyl ester with an aryl halide occurs in high yield with 1% [Pd]−5 as catalyst, and 2% AgOTf as additive in toluene at 50 °C. Scope of α-arylation of cyclobutyl t-butyl esters Experiments on the scope of the α-arylation of cyclobutyl ...