The structure of complex 3 was confirmed by X-ray crystallography. It has been found to crystallize in the triclinic system with space group P-1 and unit cell parameters: a = 10.207(5) , b = 13.027(5) , c = 16.269(5) , α = 100.054(5) , β = 99.228(5) and γ = 97.234(5)...
The differences in catalytic performance are attributed to the effects of composition and structure. The high activity of nest-like is due to the high concentration of oxygen adspecies and good mobility of oxygen species, whereas the poor performance of dendritic-like is due to the presence of ...
(II), Zn(I1) or Mn(I1) and p-Cl.BzH.THSMC are exothermal reactions (Table 1) which corroborates the earlier inferences that low temper- ature is favourable for complexation.Pooling earlier considerations on the systems the following structure of the metal-p-Cl.BzH.THSMC complexes is ...
It was found that Ce mainly enters the tunnel structure of OMS-2 instead of K, Co mainly substitutes for Mn in the framework, and V is likely to substitution into both the Mn and K in the cryptomelane tunnel structure. The length of OMS-2 rods decreases with the decline of K+mole ...