Alcoholysis of W(OMe)6 afforded (p-PhCH2OC6H4O)6W (1-OCH2Ph), which could be hydrogenated (10% Pd/C, 1 atm H2) to prepare (p-HOC6H4O)6W (1-OH). Related alcoholyses of WCl6 with HOC6H4-p-X provided the hexaphenoxides (p-XC6H4O)6W (1-X, X = H, CH3, OCH3, ...
The bulk photopolymerization of methyl methacrylate (MMA) with para-substituted phenylsilanes such as F-C6H4SiH3 (1), H3C-C6H4SiH3 (2), and H3CO-C6H4SiH3 (3) was performed to produce poly(MMA)s containing the respective silyl moiety as an end group. For all the hydrosilanes, the polyme...
Through the reaction of Co-2(CO)(8) with two heterocyclic ligands of C(S)NHP(S)(C6H4OCH3)OC(Ph)CH(L-1) and C(S)NHC(CH)P(S) (Cl)N(Ph) (L-2), the two trinuclear cobalt carbonyl sulfur clusters, Co-3(CO)(7)(mu(3)-S) [mu, eta(2)-(CNP)-N-.-P-.(S) (...