The reduction of [Cp'''Ni(eta(3)-P-3)](1; Cp''' = eta(5)-1,2,4-tBu(3)C(5)H(2)) with potassium produces the complex anion [(Cp'''Ni)(2)(mu,eta(2:2)-P-8)](2-) (2), which contains a realgar-like P-8 unit. The anionic triple-decker sandwich complex [(Cp'''...
Protonation of the Mes* compound with either [H(OEt2)2][B{3,5-C6H3(CF3)2}4] or HBF4·OEt2 gives the cationic phosphinidene complex [Mo2Cp2(µ-H)(µ-PMes*)(CO)4]+ in high yield. In contrast, protonation of the analogous hydride compounds with Mes or Cy substituents...
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Protonation of Cp2TaH(CO) (Cp = C5H5, 1a; C5H4But, 1b) by HBF4·Et2O at 78°C in CH2Cl2 affords [Cp2TaH2(CO)]BF4 (2, 3) as mixtures of 2 isomers. The minor ones (2a, 2b) contain the known trans-dihydride [Cp2TaH2(CO)]+ cations whereas th... S Sabo-Etienne,V Rodrig...
The reaction of equimolar amounts of C(eta(5)-C5Me5)(CO)(2)FeP=C(NR21)R-2] (2a: NR21=NMe2, R-2=Ph; 2 b: NMe2. tBu; 2 c: NC5H10, Ph) and etherial HBF4 gave ... LHTKS Weber - 《Zeitschrift Fur Anorganische Und Allgemeine Chemie》 被引量: 0发表: 2000年 Sulphona...
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WETRON控制模块TBU5.21V2-R1-I1 LIFASA-0094FMD3850 14637 50KVAR(380V) FSG-0180SL3002-PK1023D-MU/I *LENORD+BAUERGEL260-VN00500B731 5分钟报价RADIO-ENERGIERE.0444R2B2X0.06EG KTRKupplungstechnikGmbH联轴器EDL50/50-141260x800x50x50 *EMGDMC-U003 ...