这与磷的外层电子有关,磷外层电子是5和,达到八个稳定,所以氰化物为PH3;磷化氢是一种无色、剧毒、易燃的储存于钢瓶内的液化压缩气体。该气体比空气重并有类似臭鱼的味道。如果遇到痕量其它磷的氢化物如乙磷化氢,会引起自燃。磷化氢按照高毒性且自燃的气体处理。吸入磷化氢会对心脏、呼吸系统、肾、肠...
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主要原子写在前面。P在前,H在后是沿用了有机化学上的习惯,有机化学中,喜欢把主要原子写在前面,再用H来补位,比如CH4,SiH4。磷化氢是一种无色、剧毒、易燃的储存于钢瓶内的液化压缩气体,化学式为PH3。
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【答案】:每个P-H键中的s成分为:解得α≈0.06,则p成分为0.94。孤对电子对中,s成分为1-3×0.06=0.82,p成分为0.18。成键电子对与价电子对间夹角为:解得θ≈122.6°
五配位磷化合物不很多,其中P以sp³d轨道形成PX₅(X=F,Cl,Br,Ph,OPh...)。五卤化磷中除五氟化磷PF₅外,其他均易以四配位磷存在,如固体五溴化磷PBr₅由PBr₄⁺Br⁻组成,在高介质常数的溶剂中,PBr₅电离为PBr₄⁺,Br⁻;固态五氯化磷PCl₅由PCl₄⁺PCl₆⁻组成,PCl₅和...
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