The reaction of CH 4 + Cl 2 produces predominantly CH 3 Cl + HCl, which above 1200 K goes to olefins, aromatics, and HCl. Results obtained in laboratory experiments and detailed modeling of the chlorine-catalyzed polymerization of meth... M Weissman,SW Benson - 《International Journal of Ch...
Second, oxidizing agents would be neutralized by the increased production of biofilm matrix and catalase [108]. The low antimicrobial penetration into the matrix is vastly attributed to the reaction of EPS matrix components with oxidizing agents. Since chlorine ions in electrolyzed water with high ...
The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO_2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H_2SO_4) and sodium chlorite ...
In recent years, the electrochemistry-induced reactions have drawn much attention due to the high reaction efficiency, innate scalability and sustainability of the electrolytic process41,42,43,44,45,46,47. The past decade has witnessed the rapid development of difunctionalization of unsaturated bonds i...
Chemical halogenation is an important transformation in organic synthesis. Halogenations involve the use of reactive and toxic halogens (X2) or hydrogen halides (HX). Chemical halogenations are fast and exothermic, but with little regio- or stereoselecti
Governing the oxidative addition of iodine to gold(I) complexes by ligand tuning. While several gold(I) complexes of the type (L)AuX (X = Cl, Br) are known to undergo oxidative addition of elemental chlorine and bromine (X2), respectivel... Daniel,Schneider,Annette,... - 《Dalton Tran...
A fundamental understanding of the active sites in working catalysts can guide the rational design of new catalysts with improved performances. In this work, we have followed the evolution of homogeneous and heterogeneous Pd catalysts under the reaction
Then, 100 μL of reaction stop solution was added. Absorbance was spectrophotometrically measured at a wavelength of 450 nm. The amount of 8-OHdG was calculated by comparison with a standard curve determined from standards treated similarly to the samples. In addition, both MDA and 8-OHdG ...
Fig. 1. Reaction of guanine base with hydroxyl radical. The process of lipid peroxidation is catalyzed by the iron and results in the formation of peroxyl radicals (ROO). Once formed, peroxyl radicals can be rearranged via a cyclisation reaction to endoperoxides (precursors of malondialdehyde) ...
(standard deviation) in the figure were obtained from three sampling runs.dC2synthesis over PdCu/TiO2during an intermittent 112-hour reaction with the CH4: O2ratio of 373: 1, these data were collected every 30 min.eSummary of turnover frequency (TOF) and turnover number (TON) achieved on...