Oxidation state-dependent ligand rearrangements in designed cytochromesPublication » Oxidation state-dependent ligand rearrangements in designed cytochromes.doi:10.1016/0162-0134(95)97602-MPaul D. BarkerEdmund P. NerouMyles R. CheesmanAndrew J. Thomson...
2.6), SoxCD catalyzes the six-electron oxidation of protein-bound sulfane–sulfur (oxidation state − 1) to sulfone–sulfur (+ 5) and electrons are transferred to small periplasmic cytochromes c. Notably, the Sox system lacking SoxCD still oxidizes sulfite, showing that SoxCD is not ...
Metal oxidation state and imine vibrational frequencies of reduced copper and nickel tetraimine macrocyclic ligand complexes 来自 ACS 喜欢 0 阅读量: 35 作者:RR Gagne,DM Ingle,GC Lisensky 摘要: Normal imine vibrational bands between 1500 and 1700 cm-1 are observed for copper(II) and nickel(II)...
To date, the effect of oxidation state on activity remains controversial in whether higher or lower oxidation states benefit the enhancement of catalytic activity. Herein, we discover a volcanic relationship between oxidation state and hydrogen evolution reaction activity based on Os single-atom catalysts...
Application of transient infrared spectroscopy to intramolecular energy transfer in [(phen)(CO)3ReI(NC)RuII(CN)(bpy)2]+ technique can be a powerful tool for the elucidation of oxidation state and mechanisms involving photochemical intermediates by direct observation of ligand ... JR Schoonover,...
Department of Chemical and Biological Engineering and Computation and Data-Enabled Science and Engineering Program, University at Buffalo, State University of New York, Buffalo, NY, USA Michel Dupuis Department of Materials Science and Engineering, National University of Singapore, Singapore, Singapore ...
Nature of the manganese(I)-dioxolene bonding as a function of the ligand oxidation state: UV-visible, IR, and resonance Raman spectroelectrochemical study of [Mn(CO)3Ln(Diox)]z (n = 0, 1; z = -2, -1, 0, +1) and [... F Hartl,DJ Stufkens,A Vlcek - 《Inorganic Chemistry》...
Synthesis of coordination compounds The great variety of coordinationcompoundsis matched by thediversityof methods through which such compounds can be synthesized. Complex halides, for example, may be prepared by direct combination of two halide salts (either in the molten state or in a suitable solv...
Iron-based transition metal complexes are attractive for the development of earth-abundant solar energy conversion technologies1,2,3, but traditional FeII polypyridyl complexes suffer from rapid losses of the excited state energy from initially excited metal-to-ligand charge transfer (MLCT) states to...
J. et al. Arsenic and Environmental Health: State of the Science and Future Research Opportunities. Environ. Health. Perspect. 124, 890–9 (2015). 3. Chakraborti, D. et al. Status of groundwater arsenic contamination in the state of West Bengal, India: a 20-year study report. Mol. ...