Oxidation of desoxybenzoin with 1M HNO 3 at 60掳 in 40% dioxan gives benzoin (25%), benzil (12%) and degradation products (benzoic and p-nitrobenzoic acids and benzaldehyde) (62%), while in 70% acetic acid, benzoin (46%), benzil (11%) and the degradation products (41%) are ...
The nitric acid oxidation of benzoin has kinetically been studied in 40% dioxan at 90°. The rate is independent of both concentrations of nitric and nitrous acids, and is expressed as v = k [benzoin]. The reaction is acid-catalyzed and the plot of log k vs H o gives a straight line...
Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.MAGNUS BAKKE JANLENNART HAAKANSON CHRISTER
Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.LENNART HAAKANSON,CHRISTERMAGNUS BAKKE,JAN
Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.BAKKE, JAN MAGNUSHAAKANSON, CHRISTER LENNART
Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.
Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.BAKKE, JAN MAGNUSHAAKANSON, CHRISTER LENNART