There is also a good correlation between the rates of the NBS oxidations and Br2 oxidations of these alcohols. The results are interpreted in terms of a cyclic mechanism involving a rate-determiningion of the alpha hydrogen as a hydride anion.doi:10.1139/v69-108...
Oxidation of Alcohols - The oxidation of alcohols is an important reaction in organic chemistry. The oxidation of alcohols to the corresponding carbonyl compounds, say aldehyde or ketone, plays a central role in organic synthesis. Learn about the Lucas t
e.g. Class III (whichoxidizes higher alcohols but also functions as glutathione-dependent formaldehyde dehydrogenase). However, the enzymes in all these classes use NAD(P) as coenzyme and are structurally related, a form of Class III most probably being the ancestor of this large family of ...
Wietzerbin, K,Bernadou, J,Meunier, B.Mechanism of the Catalytic Oxidation of Tertiary Alcohols by the Water-Soluble Mn-TMPP/KHSO5 System:β-Fragmentation veursus O-Neophyte Rearrangement. European Journal of Inorganic Chemistry . 1999Wietzerbin, K,Bernadou, J,Meunier, B.Mechanism of the ...
Ji-Dong Lou,XiuLian Lu,Li-Hong Huang,Qiang Wang,Xiao-Nan Zou.Effective Oxidation of Alcohols under Heterogeneous Conditions with a New Reagent: Manganese Dioxide Supported on Graphite[J]. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry .2011(10)...
Specifically, oxidation of alcohols to the corresponding aldehydes and ketones is one of the most important functional group transformations in organic synthesis. Several catalytic processes using transition metal complexes and toxic oxides have been reported, but these processes employ stoichiometric or ...
These alcohols are the main contributors to oxidative age hardening of high sulfur asphalts. Analysis of the kinetic data for ketone and sulfoxide formation during asphalt oxidation also provides additional evidence for the validity of the dual asphalt oxidation mechanism previously reported.doi:10.1080/...
alcohols (acyclic compounds)doi:10.1002/chin.197446168NATARAJAN R.VENKATASUBRAMANIAN N.Chemischer InformationsdienstNatarajanR and Venkatasubramanian N, Kinetics and mechanism of oxidation of secondary alcohols by potassium bromate, Tetrahedron 1974; 30(16): 2785-2789....
Anticipating a new mechanism of oxidation for the catalyst MTO, we undertook a study of the oxidation of alcohols by MTO and hydrogen peroxide. (1) March, J. AdVanced Organic Chemistry: Reactions, Mechanisms, and Structure, 4 ed.; John Wiley & Sons: New York, 1992. (2) Larock, R. C...
+ Since Nakagawa, Konaka, and Nakata' previously found that nickel peroxide was a useful oxidizing agent on the oxidation of alcohols, a lot of the reactions using nickel peroxide have been reported. That is, on the oxidation of amines12phenols13 hydrazones,' sulfur compoundsls nitriles16 and...