2A, C). Knockdown of cofilin1 prevented cell damage after 16 h of erastin or glutamate exposure (Fig. 2E). Further, deletion of cofilin1 reduced the number of Annexin V and propidium iodide (PI)-positive cells upon erastin or glutamate exposure (Fig. 2F, G). The xCELLigence real-time...
In general, trends in average Mn oxidation state before ~600 Ma are less certain due to larger uncertainties caused by the smaller number of preserved deposits. An exception to this uniformly low oxidation state is an increase from +2 to greater than +2.5 in the average oxidation state of...
Especially, when pure CoFe2O4 was used as catalyst; excellent results with turnover number of 288 and 92.4% selectivity for cyclohexanone and cyclohexanol was obtained under 1.6 MPa of initial oxygen pressure at 418 K after 6.0 h of reaction. The influences of initial oxygen pressure, ...
physical and chemical properties of Ru-based oxidation catalysts, then summarising the catalytic oxidations which they accomplish. More detail on these is given in the succeeding four chapters. The major oxidants RuO4(1.2.1), perruthenate [RuO4]−(1.3.1) – mainly TPAP, (...
The high reactivity of the CeO2 surface and the presence of vacancies in combination with noble metal species make these systems highly active in a number of catalyzed reactions, such as CO oxidation, NOx reduction and CH4 oxidation [5,27,28]. Pd is increasingly used in these applications ...
Capsaicin increased the gene expression of carnitine palmitoyltransferase 1 and the β-oxidation of palmitate. Furthermore, capsaicin significantly reduced palmitate-stimulated activation of c-Jun N-terminal kinase, c-Jun, and p38. Our data suggest that the attenuation of palmitate-induced MIP-1 and ...
The status of iron as the most important and versatile metal in biological redox chemistry can be traced to a unique underlying inorganic chemistry. Essential to understanding this chemistry are the basic concepts of oxidation state, coordination number, spin state and ligand field effects. Their ...
Enantioselective organo-SOMO catalysis has, in the last two years, been the subject of considerable development and exploration. A number of new and unique... K.,C.,Nicolaou,... - 《Journal of the American Chemical Society》 被引量: 204发表: 2009年 The chemical oxidative polymerization of ...
in Methods and all sequences are provided in Supplementary Dataset3. Each node was colored by ultrafast bootstrap support percentage (1000 replicates) and the scale bar indicates the average number of substitutions per site. The tree showing all taxa is provided in Supplementary Dataset5. ...
to the Mn-Mn shell. EXAFS data fitting suggests that the coordination number of O for bulk α-MnO2and MnO2-P is 6.0 and 5.2, respectively, while that for MnO2-D is only 3.0, confirming the significant decrease of Mn-O coordination (Supplementary Table3). Figure1dprovides a cartoon ...