As far as the chemistry of organic carbonates conversion is concerned, the development of innovative setups and technologies (such as reactive distillation or microwave irradiation) strongly promoted the expansion of processes based on organic carbonates conversion. Thus, it is reasonable to expect that...
Solid state coordination chemistry: temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO2(O3PC6H5)(HO3PC6H5)], [{Cu3(bpy)3(H2O)}V4O9(O3PC6H5)4], [{Cu(bpy)}2...
In this reaction, for the transport of water, toluene and nitrogen gas and water are collected in the dean stark and returned to the toluene reaction medium with reflux. Toluene at 175 degrees is removed by vacuum. But the toluene smell remains in the ester. Which solve...
Added additional 30 mL of ethoxyethanol and reflux was continued for 48 hrs, then the reaction mixture was cooled down to room temperature. The crude material was used without additional purification in the next step. Step 5 Iridium dimer suspended in ethoxyethanol was mixed under nitrogen ...
This complex was prepared with slight modifications to literature methods9,28. Re(CO)5Cl (0.3020 g, 0.83 mmol) was dissolved in 50 ml of hot toluene, then 2,2-bipyridine (0.130 g, 0.83 mmol) was added, the mixture was stirred and reflux for 1 h to get yellow product...
The relative internal energies were computed for each possible topology (Fig.2b, right; Supplementary Note2). Since the cages are formed by reversible imine chemistry, one might expect thermodynamic products to be formed—that is, the topologies with the lowest relative internal energy. These calcul...
Post catalytic characterization clearly supports the heterogeneous and recyclable nature of the catalyst.doi:10.1002/asia.201901277Tanmoy BiswasArjun HalderKhusboo S. PaliwalAntarip MitraGouri TuduRahul BanerjeeVenkataramanan MahalingamJohn Wiley & Sons, LtdChemistry – An Asian Journal...
This article comprehensively overviews the designed chemistry of MOF-composites for metal-ion batteries (MIBs) and metal-ion capacitors (MICs). The synthesis and properties of various composites involving MOFs, including MOF-MXene, MOF-carbon nanomaterials (CNM)/graphene/carbon, MOF-transition metal ...
The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) distributions of the 2CbzTAZ were simulated utilizing the popular B3LYP-D3/6-31 + G* model chemistry for molecular thermochemistry, as shown in Fig. 1. The simulation plot clearly indicates that the...
Organic reactions driven by microwaves have been subjected for several years to some enigmatic phenomenon referred to as the microwave effect, an effect often mentioned in microwave chemistry but seldom understood. We identify this microwave effect as an electromagnetic wave effect that influences many ...