In this study, 12 solvents were investigated, where the addition of chlorobenzene, benzene, xylene, and toluene lead to uniform films over the entire substrate. The kinetic control of nucleation by the fast solvent wash has generated a similar approach through vapor-assisted film formation [188],...
Strong light-matter coupling provides the means to challenge the traditional rules of chemistry. In particular, an energy inversion of singlet and triplet excited states would be fundamentally remarkable since it would violate the classical Hund’s rule. An organic chromophore possessing a lower singlet...
Mn2(2,5-Disulfhydrylbenzene-1,4-dicarboxylate): a microporous metal–organic framework with infinite (–Mn–S–)∞ chains and high intrinsic charge mobility. J. Am. Chem. Soc. 135, 8185–8188 (2013). Article CAS PubMed Google Scholar Wang, M., Dong, R. & Feng, X. Two-dimensional...
Volatile organic compounds (VOCs) are considered one of the significant contributors to air pollution because they are toxic, difficult to remove, come from a wide range of sources, and can easily cause damage to the environment and human health. There i
Chlorinated organic compounds (COCs) are common anthropogenic contaminants encountered in soil and groundwater. COCs were industrially produced for different applications, such as dry cleaning, degreasing, or as pesticides. The presence of COCs in the en
A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g 1 of CO 2 , 9.9 mg g 1 of...
Unsaturated organic compounds containing C˭C groups (as in benzene ring) display relatively low redox potentials (<1.0 V vs Li/Li+) and high specific capacities, and they are good choice of active anode materials for all-organic symmetric batteries [26], [27]. Ladder polymers possessing...
Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene Three new complexes, namely [Zn(mbix)(SO4)]路CH3OH (1), Cd(mbix)2(NO3)2 (2) and [Cd(mbix)2(H2O)2]路(NO3)2 (3), have been obtain...
11,12. So far, heterogeneous catalysis has been involved to neutralize volatile organic compounds13,14,15. Small organic molecules like phenol, benzene, toluene, butyraldehyde and triclocarban were treated with DBD plasma in the presence of metal-oxides as catalysts, includingTiO2,MnO2,Fe2O3andCeO...
we speculate that PTA molecules and Ni2+are initially anchored on the edge of graphitic surfaces where nascent MOFs were yielded. Then, with the stiffness of the organic linkers provided by the benzene ring of PTA molecules, the epitaxial growth of the rest of metal ions and organic linkers ...