一种聚吡咯@ZIF8/石墨烯纳米复合材料的制备方法及应用,本发明制备时利用PPy作为GAs和ZIF8之间的桥梁,加强结合,通过原位生长方法成功合成PPy@ZIF8/GAs复合材料,使体系的催化活性超过了单组分系统,了纳米材料的电化学特性,本发明成功合成了PPy@ZIF8/GAs纳米复合材料 mof材料 PDMS/PCN-222@NWF复合材料 CQDs/PCN-224...
Millange, F., Ferey, G., Morcrette, M., Serre, C., Doublet, M. L., Greneche, J. M. and Tarascon, J. M. Towards the reactivity of MIL‐53 or FeIII(OH)0.8F0.2[O2C‐C6H4‐CO2]versus ...
基于此,中山大学李光琴课题组提出了一种新的方法,将NH2-MIL-53(Al)衍生为表面分散有配位不饱和非晶Al位点的纳米纤维膜(Al-NFM),并将其用于电催化NO还原为NH2OH以及NH2OH直接转化为吡啶肟类化合物。 实验结果表明,所制备的Al-NFM催化剂能够直接将电还原NO制备的NH2OH转化为吡啶-2-醛肟,该产物的法拉第效率和产率...
Six new functionalized vanadium hydroxo terephthalates [VIII(OH)(BDC-X)]·n(guests) (MIL-47(VIII)-X-AS) (BDC = 1,4-benzenedicarboxylate; X = −Cl, −Br, −CH3, −CF3, −OH, −OCH3; AS = as-synthesized) along with the parent MIL-47 were synthesized under rapid microwav...
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基于此,中山大学李光琴课题组提出了一种新的方法,将NH2-MIL-53(Al)衍生为表面分散有配位不饱和非晶Al位点的纳米纤维膜(Al-NFM),并将其用于电催化NO还原为NH2OH以及NH2OH直接转化为吡啶肟类化合物。 实验结果表明,所制备的Al-NFM催化剂能够直接将电还原NO制备的NH2OH转化为吡啶-2-醛肟,该产物的法拉第效率和产率...
Bellat, MIL-53(Al) under reflux in water: formation of gamma-AlO(OH) shell and H2BDC molecules intercalated into the pores. Microporous Mesoporous Mater. 183 , 156–161 (2014)Bezverkhyy, I. et al. MIL-53(Al) under reflux in water: formation of g-AlO(OH) shell and H2BDC molecules...
Millange, F., Ferey, G., Morcrette, M., Serre, C., Doublet, M. L., Greneche, J. M. and Tarascon, J. M. Towards the reactivity of MIL‐53 or FeIII(OH)0.8F0.2[O2C‐C6H4‐CO2]versus ...
Al-OH groupsAdsorptionMoistureA series of highly-hydrophobic MIL-53-Al (MIL= Materials of Institut Lavoisier) frameworks synthesized via decoration of the Al-OH groups by alkyl phosphonic acid were developed as adsorbents for removing acetone from humid gas streams. The newly prepared materials were...
et al.Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C–C6H4–CO2) (M=Al3+, Cr3+), MIL-53. Chemical Communications . 2003Feŕ ey, G.; Latroche, M.; Serre, C.; Millange, F.; Loiseau, T.; Percheron-Guegan, A. Hydrogen Adsorption in the Nanoporous Metal-...