Methods of calculation for the parameters Dq and B from the ligand-field spectra of octahedral cobalt(II) compounds are discussed. A method of calculation is introduced, which considers the lowering of the 4T1g (F) state by spin-orbit splitting. This calculation is applied to the spectra of ...
The orbital splitting of 2D term from the d9 configuration can be obtained from d1. • Since the d9 configuration corresponds to a single hole in the filled d10 shell, the effect of the ligand field can be derived from those of d1 configuration by imagining the electron to have a pos...
Theoretical investigation shows that OR in Sr2RuO4 originates from the surface electric field, which can be tuned via the screening effect of the overlaid K layer. This work establishes not only that variation in the OR angle can be induced by an electric field, but also provides a way to...