Nucleophilic substitution at C, Si and P: How solvation affects the shape of reaction profiles - Bochove, Bickelhaupt () Citation Context ...ghest level for which we could obtain the energies directly, CCSDT/atz (see Table 1), this leads to an energy profile of this gas-phase reaction ...
Primary alkyl halide - has a carbon with two hydrogens Secondary alkyl halide - has a carbon with one hydrogen Tertiary alkyl halide - has a carbon with no hydrogensHaloalkanes can undergo two types of substitution reactions:Tertiary haloalkanes undergo SN1 reactions while secondary and primary...
Some questions on the interpretation of the effects of sodium azide on nucleophilic substitution in the mechanistic borderline regionBeckett AH, Chidomere EC.doi:10.1016/S0040-4039(01)82181-XGeorge A. GregoriouChemistry Department, N.R.C. “Democritos,” Greek Atomic Energy Commission, Athens, ...