A molecular orbital energy level scheme is estimated which is able to account for both the "crystal field" and the "charge transfer" spectra of VO(H2O)(5)(2+) and related vanadyl complexes. The paramagnetic resonance g factors and the magnetic susceptibilities of vanadyl complexes are discussed...
Nuclei, which have positive charges, must collide at extremely high speeds to overcome the Coulomb barrier. The speed of particles in a gas is governed by the temperature. At the very center of the Sun and other stars, it is extremely hot and density is very high. For the Sun, the tem...
Charge compensation of divalent and trivalent cations was expected to occur via the oxidation of U4+ to higher valence states (U5+ or U6+). Gd3+ was added to act as a neutron absorber in the final Pu bearing wasteform. X-ray powder diffraction of synthesised specimens found that phase ...
The proper technical base and equipment for direct charge measurement are avail- able only at a limited number of experimental sites. To determine the beam intensity by using monitor reactions requires in principle exact knowledge of the incident energy on the monitor foils. In most cases the ...
“Charge equilibration” mechanism, a very relevant aspect in connection with the role of MNT reactions in nuclear structure studies [2]. Experimental works involving\(\gamma \)-ray detection, following MNT in both aforementioned regimes, initially focused on evaluating the degree of spin ...
E. Unravelling the influence of quantum proton delocalization on electronic charge transfer through the hydrogen bond. Chem. Phys. Lett. 678, 289–295 (2017). Article CAS Google Scholar Hollas, D., Muchova, E. & Slavicek, P. Modeling liquid photoemission spectra: path-integral molecular ...
Liquid–liquid extraction is an efficient methodology for partitioning a mixture of elements where differences in charge and/or polarity of elements or complexes in solution can be exploited, for example, the use of polar aqueous and non-polar organic systems, which are immiscible or only moderately...
(ii) the energy of the 3d manifold given by the effective nuclear charge of the metal ion within the ligand environment, and (iii) the changes in the electronic and geometric structure on oxidation (i.e., electronic and geometric relaxation, where the latter corresponds to a reorganiza...
As an NSUF, the services associated with university-led experiment irradiation and post-irradiation examinations are provided free-of-charge. The U.S. DOE is providing these services to support U.S. leadership in nuclear science, technology, and education and to encourage active university/industry...
The direction-dependent liquid argon charge recombination model by Cataudella et al. was adopted and a likelihood statistical analysis was performed, which gave no indications of significant dependence of the detector response to the recoil direction. The aspect ratio R of the initial ionization ...