药材来源(中文) 檀香 药材来源(英文) Santalum album 药材来源 Sandalwood 化学成分名称(英文) Nuciferol CAS号 1786-15-8 结构式 SMILES分子结构 CC1=CC=C(C=C1)[COOH](C)CC/C=C(\\C)/CO AI活性预测 查看 成药性预测 查看 扩展信息 ...
Using (S)-benzyl 2,3-epoxypropyl ether (1), the first stereoselective synthesis of (+)-nuciferol (14) and (+)-nuciferal (16) has been achieved. Employing the same methodology an enantioselective synthesis of (+)-α-curcumene (17) is also described....
ChemInform Abstract: A Total Synthesis of Nuciferal and NuciferolterpenesNo abstract is available for this article.doi:10.1002/chin.198921283W. Y. LEEDep. Chem., Seoul Natl. Univ., Seoul 151‐742Y. Y. LEEDep. Chem., Seoul Natl. Univ., Seoul 151‐742K. LIM...
Enantiomerically pure α-hydroxy, α,β-dihydroxy and α,β-epoxyaldehydes, useful building blocks for the synthesis of acyclic oxygenated fatty acids metabolites, were synthetized via epoxybutanediol acetonide starting from the commercially available L-ascorbic and D-isoascorbic acids....
ChemInform Abstract: A STEREOSPECIFIC SYNTHESIS OF (+‐)‐(E)‐NUCIFEROL VIA THE (2,3)‐SIGMATROPIC REARRANGEMENT OF ALLYLIC SULFOXIDESalcohols (benzene compounds)Aus der β-Methyl-4-methyl-zimts
ZhenTingDU XueGongSHE GuoRenYUE JunYingMA YangLI XinFuPAN中国化学快报(英文版)Du, Z.T.; She, X.G.; Yue, G.R.; Ma, J.Y.; Li, Y.; Pan, X.F. Enantioselective synthesis of (+)-nuciferal, (+)-(E)-nuciferol and (+)-alpha-curcumene by chiral hydrogenesterification reaction. Chin....
Concise asymmetric total syntheses of (-)-nuciferol, (-)-nuciferal, and (-)-dihydrocurcumene via Rh(I)-catalyzed boronic acid addition(E)-Crotonatep-Tolylboronic acidRh(I)-catalyzedCatalytic asymmetricBisabolane sesquiterpenesA general catalytic asymmetric total synthesis of aromatic bisabolane ...
A general catalytic asymmetric total synthesis of aromatic bisabolane sesquiterpenes, (-)-nuciferol (ent-1c), (-)-nuciferal (ent-1d), and (-)-dihydrocurcumene (ent-1h) have been achieved in 5-6 steps in high chemical yields from commercially available (E)-ethylcrotonate. A key ...