Noyori-type catalysts have found numerous applications in research and industrial settings. The central mechanistic component of such catalysts is a metal centre coordinated to a N–H moiety. This amino moiety has traditionally been thought to participate directly in catalytic reactions by serving as ...
Noyori-type catalysts have found numerous applications in research and industrial settings. The central mechanistic component of such catalysts is a metal centre coordinated to a N–H moiety. This amino moiety has traditionally been thought to participate directly in catalytic reactions by serving as ...
Noyori-type catalysts have found numerous applications in research and industrial settings. The central mechanistic component of such catalysts is a metal centre coordinated to a N–H moiety. This amino moiety has traditionally been thought to participate directly in catalytic reactions by serving as ...
Wang,K. Ding.Generation of self-supported noyori-type catalysts using achiral bridged-BIPHEP for heterogeneous asymmetric hydrogenation of ketones. Advanced Synthesis and Catalysis . 2006Generation of self-supported noyori-type catalysts using achiral bridged-BIPHEP for heterogeneous asymmetric hydrogenation ...
Wang,K. Ding.Generation of self-supported noyori-type catalysts using achiral bridged-BIPHEP for heterogeneous asymmetric hydrogenation of ketones.Advanced Synthesis and Catalysis. 2006Liang Y X,Wang Z,Ding K L. Generation of self-supported Noyori-type catalysts using achiral bridged-B1PHEP for ...
We herein report on solution structural studies of RuⅡ catalysts (3a, 9) composed of achiral bisphosphine ligands (4, 8) and the enantiopure 1,2-diphenylethylenediamine (DPEN). Complete chiral induction from enantiopure (R,R)-DPEN to achiral bisphosphine ligand 3a was observed in solution, ...
Chemistry: A European journalA Highly Enantioselective Access to Tetrahydroisoquinoline and β-Carboline Alkaloids with Simple Noyori-Type Catalysts in Aqueous Media. Evanno L,Ormala J,Pihko P M. Chemistry A European Journal . 2009A Highly Enantioselective Access to Tetrahydroisoquinoline and β-...
Solution Structure and Behavior of Benzophenone-based Achiral Bisphosphine Ligands in Noyori-Type Ru(II)-Catalystsdoi:10.1002/cjoc.200790217asymmetric catalysischiral inductionNMRhydrogenationketonebisphosphinerutheniumQing JingState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry...
This minireview discusses the accelerative role of alkali metal alkoxides in two important catalytic processes: hydrogenation of ketones and esters with Noyori-type molecular catalysts. Here I offer my perspective on the unique mechanistic aspects of these reactions - a subject that remains ...