Previously, the activation of small molecules by cyclic alkyl(amino) carbene (cAAC)-stabilized complexes of transition-metal atoms in their zero oxidation state and two- coordination geometry has been visualized due to the fine tuning of the σ-donation and π-accepting property of cAAC. The auth...
Kinetic parameters The study investigates the removal of H-atoms from 3M1P by OH• using the mechanism proposed by Singleton and Cvetanovic77. This reaction is assumed to proceed by a two-step mechanism78, involving a rapid pre- equilibrium between the reactants and a pre-RC species, ...
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Methylsemicarbazide (MSC) was successfully demonstrated as a suitable building block in the formation of 25 new energetic coordination compounds (ECC). The further clever selection of late 3d metals, co-solvents and anions yielded a wide choice of different functional materials partly suitable for las...
T. M. Electrocatalytic reduction of nitrate on a Pt electrode modified by p-Block metal adatoms in acid solution. ChemCatChem 5, 1773–1783 (2013). 3. Paredis, K. et al. Evolution of the structure and chemical state of Pd nanoparticles during the in situ catalytic reduction of NO ...
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Excerpts: After nearly 30 years of arguing that a black hole destroys everything that falls into it, Stephen Hawking is saying he was wrong. It seems that black holes may after all allow information within them to escape. (...) It was Hawking's own work that created the paradox. In 19...
Of the 18,012 reflections measured, 2550 were unique (Rint = 0.030), and of these, 2356 data satisfied the I ≥ 2σ(I) criterion of observability. The structure was solved by direct methods [9] and refined (anisotropic displacement parameters and C-bound H atoms in the riding model ...
The NOESY spectrum indicated that the hydrogen atoms at 10b and 3a were oriented towards one side and to the side opposite to the hydrogen atom at 2. This finding was supported by observation of the hydrogen atoms at 3 and 3′. NOESY interactions were observed only between the hydrogen ...
While the ECC contribution is smaller than that from ELC at high projectile velocities (V p >3 au) the data suggest that ECC will dominate belowV p =2.8 au. The relevance of the results to the projectile velocity dependence of existing capture theories is discussed....