Question: Nitrosyl chloride (NOCl2) is highly toxic.a. (GO2A) Draw the best Lewis structure for this moleculeb. (GO2B) Identify the electron group geometry, molecular geometry, and bond angle.Electron group geometry =Molecular geometr...
Recently we reported the formation of the chloride-bridged dinitrosyl complex [Mo2Cp2(μ-Cl)(μ-PtBu2)(NO)2] (3a) from the corresponding dicarbonyl complex [Mo2Cp2(μ-Cl)(μ-PtBu2)(CO)2] (1a), in a two step process involving an intermediate species (presumably [Mo2Cp2Cl(μ-PtBu2)(...
This reacts with NaBH, to yield Cp*IrH(PPh,)(N,Ar) (4) in which the ArN, ligand has switched to the doubly bent geometry, on the basis of the 1 5 ~ , NMR chemical shift data. Attempts to synthesize the corresponding chloro analogue 5 resulted in only the chloride salt of the ...