Nitrogen-Nitrogen Double Bond Cleavage of Azobenzene by a Triruthenium Pentahydrido Complex , Hydrogenation of Azobenzene and 1 , 2-DiphenylhydrazineNakajima, YumikoSuzuki, Hiroharu
radiolysis of PVA was initiated by liberation of H and OH groups leading to scission of the main chains and formation of carbonyl and double bond groups... NM El-Sawy,MB El-Arnaouty,AMA Ghaffar - Journal of Macromolecular Science: Part D - Reviews in Polymer Processing 被引量: 26发表: ...
Polymerization of one of the carbon-nitrogen double bonds in carbodiimides has been effected with n -butyllithium catalyst in hydrocarbon solvents at 25°C. Monomers converted to polymer include diethylcarbodiimide, di- n -butylcarbodiimide, di- n -hexylcarbodiimide, diphenylcarbodiimide, diallyl...
Compound (I) containing at least different multiple bonds of N=N-double bond, which is irradiated with polarized light to cause preferred orientation of (I), where stimulation of the multiple bonds cause permanent structure or photo chemical reaction with the formation of a reaction product; and...
These reactions are proceeding by rate-determining nucleophilic attack by the alkoxide ion on the carbon–nitrogen double bond (AN# + DN). The restricted stereochemistry of the tetrahedral intermediates suggests that the E-hydroximoyl bromide and chloride may be undergoing unassisted ionization to ...
Herein, we demonstrate the solution preparation of free-standing nitrogen-doped amorphous monolayer carbon with mixed five-, six- and seven-membered (5-6-7-membered) rings through the polymerization of pyrrole within the confined interlayer cavity of a removable layered-double-hydroxide template. ...
摘要: The carbon-nitrogen double bond can be conveniently reduced by reaction of the appropriate organic (or organometallic) compound with a mixture of triiron dodecacarbonyl [Fe3(CO)12] and methanol in benzene.DOI: 10.1021/jo00797a056 被引量: 23 ...
Various Schiff bases have been prepared to study base induced carbon-nitrogen double bond migrations. Schiff bases derived from aliphatic aldehydes display highest selectivity. Hydrolysis of the resulting rearranged Schiff base provides an entry to make amines from aldehydes. The reaction has possible pra...
2). The formation of the ∗–OOH intermediate, where ∗ denotes an active site of the catalyst, and then the breaking of the O–OH bond will lead to H2O formation whereas the bond breaking of the ∗–OOH will produce H2O2 (Fig. 2).8 Interestingly, the O–OH breaking is always ...
ChemInform Abstract: The Element‐Nitrogen Double Bond in Cations of Cyclic Bis(amino)phospha‐, ‐arsa‐, ‐stiba‐, and bismuthinesorgano‐antimony compounds, nonmetal heterocyclesorgano‐phosphorus compounds, nonmetal heterocyclesorgano‐bismuth compounds...