Our DFT data elucidates clearly the reason why the major product of nitrobenzene reduction reaction was aniline. Furthermore, the adsorption/desorption of phenyl group was found to have significant impacts on kinetic barriers. Generally, in the hydrogenation process (N-H or O-H bond association),...
Biochar-supported ZVI have received increasing attention for their potential to remove nitrobenzene in groundwater and soil. However, the capacity of this material to enhance the biological reduction of nitrobenzene and alter microbial communities in ana
reduction of nitrobenzene to aniline by intestinal microflora, its reduction to aniline occurring in hepatic microsomes and erythrocytes, and nitrobenzene oxidative metabolism to the nitrophenols by hepatic microsomes. Many of the toxicological effects are likely triggered by metabolites of nitrobenzene. For...
Nitrobenzene(98-95-3) is used to manufacture aniline and to producelubricating oilsor used as a solvent. It can causemethemoglobinemiawith consequent hemolyticanemia, splenic congestion, liver, bone marrow, and spleen hematopoiesis. In addition, it can also affect the central nervous system and th...
It has been shown that the formation of aniline occurs when solvato complexes of vanadium(III) (γPhNH 2 =18.1·10 −3 ) and vanadium(IV) (γPhNH 2 = 2.84·10 −3 ) are added to the system. The photocatalytic reduction of nitrobenzene is accompanied by oxidation of the alcohol ...
n.a poisonous oily water-soluble liquid used as a solvent and in the manufacture of aniline nitrobenzene同义词 n. [有化]硝基苯 mirbane nitrobenzene_医学行业词汇 硝基苯:一种有毒的苯衍生物,分子式为C 6H 5NO 2,为无色至淡黄色油样液体 用于制造苯胺 nitrobenzene_石油行业词汇 硝基苯 nitrobenze...
reduction, hydrogenationAromatic nitro compounds are effectively reduced to anilines by triethylsilane using Wilkinson''s catalyst.doi:10.1080/00397919608003701Brinkman, Herbert R.Miles, William H.Hilborn, Michael D.Smith, Michael C.Taylor & FrancisSynthetic Communications...
Related to Nitrobenzenes:nitrobenzene poisoning ni·tro·ben·zene (nī′trō-bĕn′zēn′, -bĕn-zēn′) n. A colorless or yellowish poisonous oily liquid, C6H5NO2, having the odor of almonds and used in the manufacture of aniline, insulating compounds, and polishes. ...
highlights their potential for achieving desired products. The unexpected product 4-nitro-N-phenylaniline6 gwas obtained with a yield of less than 20%. It appears that the formation of6 gcan be attributed to the reduction of2ato aniline5dwithin the system, followed by its subsequent reaction...
SO42-Bi2O3-Al2O3催化水合肼还原硝基苯制备苯胺SO42-Bi2O3-Al2O3-CATALYZEDREDUCTIONOFNITROBENZENETOANILINEWITHHYDRAZINEHYDRATE 系统标签: 催化水nitrobenzenehydrazineaniline基苯hydrate 井冈山大学学报(自然科学版)30文章编号:1674-8085(2012)04-0030-04双(三环己基锡)丁二酸酯的合成、晶体结构和抑菌性质曹慧...