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On the one hand, it's yet another platform for game splintering across multiple accounts and services, thus vying for app attention in our systems. On the other, it's another competitor to the juggernaut that is Steam, but comes loaded with already-implemented social features which the latter...
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Cell-free system has emerged as a powerful platform with a wide range of in vitro applications and recently has contributed to express metabolic pathways for biosynthesis.Here we report in vitro construction of a native biosynthetic pathway for L-4-nitrotryptophan(L-4-nitro-Trp)synthesis using an...
Metal-freeRoom temperatureThe synthetic methodology adopted for nitroaldol synthesis is sustainable.The synthesized DES acted both as the solvent and catalyst.The nitroaldol products obtained were further utilized for the synthesis of nitroolefins.The nitroolefins were obtained within a very short period...
Metal-free catalyzed oxidationMolecular oxygen2-nitro-4-methylsulfonylbenzoic acidJournal of Flow Chemistry - A metal-free catalyzed oxidation of 2-nitro-4-methylsulfonatotoluene(NMST) to produce 2-nitro-4-methylsulfonatobenzoic acid(NMSBA) under Taylor flow regimes is......
ReductionCatalyst-freePhotoinducedTransborylationThe tandem reaction of photoinduced double hydrogen-atom transfer and deoxygenative transborylation for chemo-and site-selective reduction of nitroarenes into aryl amines under catalyst-free, room temperature conditions was disclosed in excellent yields. In ...
TNBC accounts for 10–15% of breast cancers that do not express estrogen and progesterone receptors (ER/PR) and are HER2-negative. TNBCs are not responsive to hormone therapies, e.g., the selective estrogen receptor modulator tamoxifen, the aromatase inhibitor anastrozole or the monoclonal ...