This review comprehensively summarized and discusses recent progress in photoinduced nickel-catalyzed enantioselective transformations with an emphasis on the reaction achievements, mechanistic insights, and structural characteristics of chiral ligands.doi:10.1016/j.ccr.2022.214479Zhilong Li...
Nickel-Catalyzed Enantioselective Dearomative Heck-Reductive Allylic Defluorination Reaction of Indoles Author links open overlay panelYuan-Yuan Hu †, Xiao-Qiu Xu †, Wei-Chao Deng †, Ren-Xiao Liang †, Yi-Xia Jia † ‡Show more Add to Mendeley Share Cite...
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation Article Open access 29 April 2024 Nickel-catalyzed acylzincation of allenes with organozincs and CO Article Open access 31 October 2023 Directing-group-free catalytic dicarbofuncti...
alkynes such as diarylacetylenes in an intermolecular manner; (2) expensive Pd- or Rh-based catalysts have been employed in all existing systems; (3) the steering of the reaction pathway exclusively toward chemoselective and enantioselective formation of allyl vinylsilanes has not yet been realized...
Put a nickel in it: Azaarylacetates and acetamides, which have been neglected as substrates in catalytic asymmetric synthesis, undergo highly enantioselective Michael additions to nitroalkenes in the presence of a chiral nickel(II)-bis(diamine) complex (see scheme; Bn=benzyl, MS=molecular sieves)...
enantioselective syntheses (incl. cis/trans-isomerism)C-C bond formationChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.doi:10.1002/chin.200738087...
The enantioselective 1,2-diboration of terminal alkenes catalyzed by platinum catalyst, combined with Suzuki coupling reactions was achieved by Morken's group9. Huang's group also reported a Co-catalyzed protocol for the formation of 1,1,1-tri- borylalkanes, but the alkene substrates are ...
Bis(pinacolato)Diboron‐Enabled Nickel‐Catalyzed Regio‐ and Enantioselective Reductive [3 + 2] Annulation of β‐Bromoenones with AlkynesAngew. Chem. Int. Ed. (IF 16.1)Wangyang Li, Yanping Zheng, Yunya Gu, Shanshan Cheng, Jinhui Xie, Yong Lu, Shanglin Chen, Qiuling Song Pub Date: 2025-...
Highly Enantioselective and Regioselective Nickel-Catalyzed Coupling of Allenes, Aldehydes, and Silanes Ng et al., " Highly Enantioselective and Regioselective Nickel-Catalyzed Coupling of Allenes, Aldehydes, and Silanes, " J. Am. Chem. Soc. 2005, 127,... Sze-Sze,Ng,Timothy,... - 《Journal...
Carbo- and heterocycles are frequently used as crucial scaffolds in natural products, fine chemicals, and biologically and pharmaceutically active compounds. Transition-metal-catalyzed cyclization of 1,6-enynes has emerged as a powerful strategy for constructing functionalized carbo- and heterocycles. Despit...