气液界面组装电致变色着色效率由于缺乏可控的成膜技术,三亚苯类金属有机框架(MOFs)材料的应用受到了限制.我们在气液界面组装了不同厚度的Ni_(3)(HITP)_(2)薄膜(HITP^(3-)=2,3,6,7,10,11-六亚氨基三亚苯),并将制备的薄膜转移到导电玻璃表面.利用X射线衍射(XRD),场发射透射电子显微镜(FETEM),场发射...
Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni3(HITP)2(HITP=2, 3, 6, 7, 10, 11-hexaiminotriph...
在中性条件下,γ-Fe2O3@Ni-HITP在CO2饱和的1 M KHCO3和0.1 M KNO3水溶液中,通过CO2和硝酸盐的共还原,表现出了最先进的尿素合成电催化性能,FEurea的收率为67.2(6)%,电流密度为−90 mA cm−2,产率为20.4(2)gh−1 g−1 cat (7.7(1) mg h−1 cm−2),比之前报道的催化剂的产率高出约5倍...
potential of the solution was measured and revealed a zeta potential of −27.2 mV (Fig. S2 in Supporting information) confirming the thermodynamic stability of the solution and the negative charge of Ni3(HITP)2, both of which facilitated the deposition. The EPD of Ni3(HITP)2was ...
利用X射线衍射(XRD),场发射透射电子显微镜(FETEM),场发射扫描电镜(FESEM),X射线光电子能谱(XPS)和拉曼光谱对样品的晶体结构,微观形貌和元素组成进行表征,采用紫外可见分光光度计以及电化学工作站对Ni_(3)(HITP)_(2)薄膜的电化学和电致变色性能进行了研究和表征.结果表明,得益于Ni_(3)(HITP)_(2)电致变色...
由于缺乏可控的成膜技术,三亚苯类金属有机框架(MOFs)材料的应用受到了限制.我们在气液界面组装了不同厚度的Ni3(HITP)2薄膜(HITP3-=2,3,6,7,10,11-六亚氨基三亚苯),并将制备的薄膜转移到导电玻璃表面.利用X射线衍射(XRD),场发射透射电子显微镜(FETEM),场发射扫描电镜(FESEM),X射线光电子能谱(XPS)和拉曼...
Characterization of Ni3(HITP)2 before and after ORR. Spectroscopic, microscopic and diffractometric techniques enabled analysis of the film before and after ORR catalysis. X-ray photoelectron spectroscopy (XPS) of catalyst films before and after catalysis revealed an increase in binding energy of ...
The as-prepared Ni3(HITP)2 presents the spindle-like shape that are regular arranged by multi-nano fibers. While utilized in LIBs, Ni3(HITP)2 can deliver the reversible capacity of 703 mAh g at 50 mA g with almost no capacity fading. According to the theoretical calculation and XPS ...
我们在气液界面组装了不同厚度的Ni 3(HITP)2薄膜(HITP 3-=2，3，6，7，10，11‑六亚氨基三亚苯)，并将制备的薄膜转移到导电玻璃表面。利用X 射线衍射(XRD)、场发射透射电子显微镜(FETEM)、场发射扫描电镜(FESEM)、X 射线光电子能谱(XPS)和拉曼光谱对样品的晶体结构、微观形貌和元素组成进行表征，采用...
Supplementary Materials: The following are available online at http://www.mdpi.com/2073-4360/10/9/962/s1, Figure S1: XPS of a Ni3(HITP)2 powder. Author Contributions: Conceptualization, Y.N. and T.K.; Methodology, D.S.; Formal Analysis, D.S.; Investigation, Y.N. and D.S.; ...