electroreduction complex Ni(DMG)2 INDO quantum chemical method.The electronic structures of the species Ni(DMG)_2, (Ni(DMG)_2)~- and (Ni(DMG)_2)_(2-) have been studied by INDO quantum chemical method. The results have clearly shown that in the first stage of the electroreduction of Ni...
The five-coordinate high-spin (S = 1) Ni2+ complex [Ni(tmc)CH3]+ (1) (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) serves as a model for a viable reaction intermediate of the A cluster of acetyl-CoA synthase (ACS) in which the distal nickel center is methylated...
complex2featured a3D network with a4-connecte{65㊃8}topological structure,and two mixed ligands of imidazole derivative ligand(bbi)and carboxylic acid ligand(H2dgc)spirally coiled out an regular pore structure.It was rather remarkable that there are also abundant hydrogen bonds in the structure,...
Structural alignment with the structure of the SerK ternary product complex (PDB code 5X0E) revealed that among SbnI homologs, the putative active site is highly conserved, whereas the remainder of the protein surface is variable (Fig. 4c). Download: Download high-res image (103KB) Download:...
Neutron diffraction structure analysis of a triply-bridged binuclear cobalt hydride complex, [(η5-Cp*)Co]2H3 Inorg. Chem., 35 (1996), p. 2698 Google Scholar (c) M. Mikuriya, S. Kida, S. Ueno, I. Murase The ability of an α-aminoisobutyric acid residue to promote helical folding ...
Hint: While naming such complex compounds it is important to take care of the part that the name of the ligands (an ion or molecule attached to a metal atom by coordination bonding is known as ligand) should be mentioned, before the name of the metal ...
Synthesis, structure, spectral and magnetic properties of a dinuclear copper(II)/nickel(II) complex bridged by glyoximate groups A new dinuclear complex of formula [(tmen)(H2O)2Ni(Hdmg)(dmg)Cu]·ClO4 (H2dmg=dimethylglyoxime, tmen=tetramethylenediamine) has been synthesized. The cryst... ...
Finally, applying the more complex repair scenario, which comprises a combina- tion of thermal impact and degradation with an application of de-icing fluid contam- ination on the CFRP adherends before being bonded, results in a reduction of the GIIC value of the joints by 80% and 83% for...
The matrix maintained its fine structure without any evidences of crystallizations or formation of medium-range ordered phase during the hydrogenation/dehydrogenation cycles. The thermal stability of our prepared metallic glassy phase used in the present study and the absence of phase transformations ...
complexNi(DMG)2INDOquantumchemicalmethod.The electronic structures of the species Ni(DMG)_2, (Ni(DMG)_2)~- and (Ni(DMG)_2)_(2-) have been studied by INDO quantum chemical method. The results have clearly shown that in the first stage of the electroreduction of Ni(DMG)_2, one ...