Ni-catalyzed Suzuki–Miyaura cross-coupling reactions of pyrimidin-2-yl phosphates, tosylates and pivalates with arylboronic acids were described. A wide array of functionalized pyrimidines have been prepared in impressive yields and show good tolerance towards wide substrate scope....
ChemInform Abstract: Ni-Catalyzed Suzuki—Miyaura Coupling Reactions of Pyrimidin-2-yl Phosphates, Tosylates and Pivalates with Arylboronic Acids.pyrimidine derivativesC-C bond formationcatalysis, phase-transfer catalysisdoi:10.1002/chin.201612187Ting
Abstract：The progress of Ni-catalyzed Suzuki cross-coupling reaction is reviewed. For all kinds of haloarenes，arene sulfonates and organoborates，with the enhancement of the activity catalyst，ligand and reducing agent，the reaction conditions become milder. The catalytic capacities of Pd catalyst and...
Synthesis of sulfone derivatives via palladium-catalyzed cross-coupling of benzyl trimethylammonium triflates and sulfonyl hydrazides Phosphorus Sulfur Silicon Relat. Elem. Mechanochemical Solvent-Free Suzuki–Miyaura Cross-Coupling of Amides via Highly Chemoselective N−C Cleavage Angew. Chem. Int. Ed. ...
(LaboratoryforAdvancedMaterialsandInstituteofFineChemicals,EastChinaUniversityofScienceandTechnology, Shanghai200237,China) Abstract:TheprogressofNi-catalyzedSuzukicross-couplingreactionisreviewed.Forallkindsof haloarenes,arenesulfonatesandorganoborates,withtheenhancementoftheactivitycatalyst,ligandand reducingagent,the...
我们今天要解读的是Baran课题组近期在Angew. Chem. Int. Ed.上发表的题为“Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids”的文章(DOI: 10.1002/anie.201605463)。作者通过把烷基羧酸做成氧化还原活性酯,在镍催化剂的作用下实现了和芳基硼酸或者烯基硼酸的交叉偶联。
3、nology,Shanghai 200237,ChinaAbstract:The progress of Ni-catalyzed Suzuki cross-coupling reaction is reviewed. For all kinds of haloarenes,arene sulfonates and organoborates,with the enhancement of the activity catalyst,ligand and reducing agent,the reaction conditions become milder. The catalytic ...
ChemInform Abstract: Magnetic Fe-Ni Alloy Catalyzed Suzuki Cross-Coupling Reactions of Aryl Halides with Phenylboronic Acidironnickelalloysmagnetic propertiesbiarylscross-couplingAlloy there matey! The inexpensive and readily prepared magnetic Fe–Ni alloy is employed in the Suzuki reactions of aryl halides...
In this paper,the synthesis routes of soluble polyfluorenes,namely oxidation by FeCl_3,Nickel(0)-catalyzed polymerization(Yamamoto coupling),and Suzuki coupling polymerization,have been reviewed. 聚芴是一种重要共轭高分子材料,文章概述了可溶解性聚芴(或芴的寡聚物)的3种典型聚合方法,即FeCl3(三氯化铁)...