inner-sphere coordinating ligands switch the activity of Ru鈥揘HC-based oxidation precatalysts in the oxidative conversion of olefins to carbonyl compounds, with the help of a series of systematically varied imidazolydene-NHC (Im-NHC) and triazolydene-NHC (Tz-NHC)-based ruthenium(II)-complexes....
Therefore, strategies for the design of efficient NHC–metal catalysts and novel asymmetric synthetic methodologies have dramatically increased over the past 10 years. Herein, the growing field of chiral NHC–metal-based asymmetric catalysis is comprehensively described....
However, the encapsulation of NHC–coinage metal complexes in a metal–organic framework (MOF) to utilize them in organic catalysis is rare. In this work, an NHC-coordinated CuBr (NHC = Bn2Im; 1,3-dibenzyl-imidazol-2-ylidene) complex was encapsulated in UiO-67 MOF ((Bn2Im)2CuBr@UiO-...
Recyclable hybrid silica-based catalysts derived from Pd-NHC complexes for Suzuki, Heck, Sonogashira reactions. Eur. J. Org. Chem. 2012, 19, 3625-3635.Borja, G., Monge-Marcet, A., Pleixats, R., Parella, T., Cattoen, X., Man, M. W. C. (2012) Recyclable hybrid silica-based ...
In this review, we present our latest developments in the field using Fe(II)-based photosensitizers bearing N-heterocyclic carbene (NHC) ligands, and their use in DSSCs. Special attention is paid to synthesis, photophysical, electrochemical, and computational characterization.View Full-TextInorganics...
Shiuh㏕zung LiuJohn Wiley & Sons, Ltd.Journal of the Chinese Chemical SocietyA Gold(I) Complex Based on 1,8-Naphthyridine Functionalized N-Heterocyclic Carbene (NHC) and Its Catalytic Activity. Zu-Yin Liu,Shiuh-Tzung Liu. JOURNAL OF THE CHINESE CHEMICAL SOCIETY . 2012...
Gold(I) NHC-based homo- and heterobimetallic complexes: synthesis, characterization and evaluation as potential anticancer agents. J. Biol. Inorg. Chem., 2015, 20(6), 1005-1020.Bertrand C, Citta A, Franken IL, Picquet M, Folda A, Scalcon V, Rigobello M, Pia L, Gendre P, Casini A...
NHC-based polytopic ligands in homogeneous catalysis: Coordination forms and tandem catalysis.Peris, Eduardo
Pd-NHC-Based Catalytic System Enables Highly Efficient [4+2] Benzannulation ReactionsZatolochnaya, O VGalenko, A VGevorgyan, V
2.1. NHC-Based Homoleptic Complexes 2.1.1. Effects of Carboxylic Groups We first decided to tune the MLCT state levels by introducing electron-withdrawing groups onto the ligands as in C2 (Scheme 1) [30]. The interest of investigating the effect of carboxylic groups was two-fold: (i) the ...