Importantly, the adsorption capacity of CO2 in the material can be improved by –NH2 as a Lewis basic group, while transferring conjugated p-electrons to the active sites of Zr-O clusters to enhance solar energy utilization[30], leading to an increase in the efficiency of CO2 reduction. ...
The NH moieties of the C2 faces of the trication are believed to hydrogen bond to the Lewis basic functional groups, as seen in the crystal structure of a hexakis(DMSO) solvate of Λ-23+ 3I. These salts rank with the most broadly applicable chirality sensing agents discovered to date....
Crystal structureThe X-ray crystal structures of Hg(C6F4X-p)2 (X = NH2, OMe, or Me) show the compounds to have almost linear C–Hg–C stereochemistry (X = NH2, 176.3(4)°; X = OMe, 179.5(2)°; X = Me, 176.3(2)°), and the two tetrafl...