(nBuCp)2ZrCl2‐catalyzed ethylene‐4M1P copolymerization: Copolymer backbone structure, melt behavior, and crystallizationmetallocene catalystethylene-4-methyl-1-pentene copolymerization12 vs. 21 insertioninterchain and intrachain composition distributions...
Hong S C,Mihan S,LilgeD,DeluxL,Rief U.Immobilized Me2Si(C5Me4)(N-tBu)TiCl2/ (nBuCP)2ZrCl2 hybrid metallocene catalyst system for the produetion of poly (ethylen-co-hexene) with pseudo-bimodal molecular weight and inverse comonomer distribution. Polymer Engineer . 2007...
(nBuCp)2ZrCl2 supported over mesoporous propyl sulfonic silica–alumina: a highly active heterogeneous catalyst for ethylene polymerizationOLEFIN POLYMERIZATIONACID GROUPSMesoporous silica-alumina functionalized with propyl sulfonic acid groups was synthesized and used as a support for MAO-(nBuCp(2))ZrCl2...
(nBuCp)2ZrCl2 supported over mesoporous propyl sulfonic silica-alumina: a highly active heterogeneous catalyst for ethylene polymerizationCasasE.ParedesB.VanGriekenR.EscolaJ. M.CATALYSIS SCIENCE AND TECHNOLOGY -CAMBRIDGE-
Carrero A, Van Grieken R, Suarez I, Paredes B. Ethylene polymerization over (nBuCp)2ZrCl2/MAO catalytic system supported on aluminosilicate SBA-15 mesostructured materials. Polym Eng Sci 2008;48(3):606-16.A. Carrero, R. V. Grieken, I. Suarez, and B. Paredes, Ethylene Polymerization over...
Atiqullah M, Anantawaraskul S, Emwas AM, Al-Harthi MA, Hussain I, Ul- Hamid A, et al. Effects of supported (nBuCp)2ZrCl2 catalyst active center distribution on ethylene-1-hexene copolymer backbone heterogeneity and thermal behaviors. Ind Eng Chem Res 2013;52:9359-73....
The polymerization of ethylene in n-heptane with (nBuCp)2ZrCl2 supported over mesoporous SBA-15 catalysts functionalized with propyl or aryl sulfonic acid groups and impregnated with either MAO or TMA was investigated and compared with reference samples. All the supports showed mesoscopic ordering ...
Galland GB, dos Santos JHZ, Stedile FC, Greco PP, Campani AD (2004) Ethylene homo- and copolymerization using (nBuCp)2ZrCl2 grafted on silica modified with different spacers. Journal of Molecular Catalysis A: Chemical 210: 149-156.
Bis(n-butylcyclopentadienyl)zirconium dichloride ((nBuCp)2ZrCl2) immobilization on magnesium dichloride adducts (MgCl2.nEtOH) and its performance in ethylene homopolymerizationFlavia D SilveiraMaria Madalena ForteJoao Henrique Dos SantosJorge Zacca
Delux, U. Rief, Immobilized Me2Si(C5Me4)(N- tBu)TiCl2/(nBuCp)2ZrCl2 hybrid metallocene catalyst system for the production of poly(ethylene-co-hexene) with pseudo-bimodal molecular weight and inverse comonomer distribution, Polym.Eng. Sci. 2007, 47, 131-139....