The reaction of RI (R = Me, Et or Pr) or [Et3O][PF6] with [NBU4]trans-[Re(CN)2(dppe)2] (dppe = Ph2PCH2CH2PPh2) affords the diisocyanide complexes trans-[Re(CNR)2(dppe)2]A (R = Me, A = I; R = Pr, A =I3; R = Et, A = PF6, whereas trans-[Re(CNH)(CNSiMe3...
Reactions of FeCl3 with LiNHMes or Li2NPh together with [(NBu4)-Bu-n][PF6] lead to the complexes (1)(infinity){[Li(THF)(2)](2)[Fe-2(mu- NMes)(2)Cl-4]} (5) and [(NBu4)-Bu-n](2)[Fe-2(mu-NPh)(2)Cl-4] (6). The structures of 1-6 were characterized by si...
Recoverable phase-transfer catalysts with fluorinated anions: Generation and reactions of dichlorocarbene and CCl3 anion in the heterogeneous system KOH(s)/CHCl3/nBu4NPF6. G. V. Kryshtal,G. M. Zhdankina,S. G. Zlotin. European Journal of Organic Chemistry . 2008...