Here, we explore the use of operando confocal Raman microscopy to investigate and quantify Li–S redox processes, based on both potentiostatic and galvanostatic measurements, achieving a detailed characterization of their reaction pathways and kinetics. By visualizing the potential-dependent reactants and...
data can be rounded to the nearest valid mixture, providing some degree of fault tolerance. In this example, the minimum Hamming distance between any two valid mixtures is\(36\), meaning that perfect recovery of the encoded data can be guaranteed even when up to 17 of the 512 compounds (...
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(throats) within the electrode structure. These features facilitate the transport of reactants and products during electrochemical reactions within the fuel cell electrode. Isolated pores in fuel cell electrodes are individual void spaces within the electrode structure that are not connected to the ...
Jiandi Wan of Rochester Institute of Technology is mimicking not only the system but the physiology of photosynthesizers by utilizing microfluidics and photochemistry to produce solar fuels. By emulating the small fluid channels seen in leaves, the device forces the reactants (CO2 and water) into...
derive the Arrhenius empirical equation and seek the nature of Ea.This paper endeavors to derive the Arrhenius empirical equations grounded upon the thermodynamic theory,and ultimately confirms that the Ea is the Gibbs free energy of resultant (-Gom,B) or Gibbs free energy of reactant (-Gom,B...
In this paper, we quantitatively interpret the Molecular Transformer, the state-of-the-art model for reaction prediction. We develop a framework to attribute predicted reaction outcomes both to specific parts of reactants, and to reactions in the training set. Furthermore, we demonstrate how to ...
An aqueous droplet (synthetic cell) with peptide and polyanion is created in a liquid of perfluorinated oil with fuel. Fuel exchange at the oil-water interface leads to a steady state that produces chemically fueled droplets. B The chemical formulas of the reactants involved in the chemical ...
Expansion Stepstaken early in the exploration impose strong constraints on the remaining exploration. However, anyExpansion Stepcan be applied on the whole CRN at any point in the protocol, meaning that any part of an explored mechanism can be studied in more detail later on with additional ...
However, the majority of these reactants necessitate operations at very high temperatures and the mechanism does not always prove to be a nucleophilic substitution. Moreover, the departure of the nitro group leads to the formation of oxygenated and halogenated derivatives of nitrogen, which are ...