] This review focuses on recent advances within the past five years regarding C–H functionalisation, namely thermochemical C(sp2)–H (thio)trifluoromethylations, photochemical C(sp2)–H trifluoromethylations, and electrochemical C(sp2)–H trifluoromethylations, using Langlois' reagent (NaSO2CF3)....
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Trifluoromethylthiolationsodium trifluoromethanesulfinatetrifluoromethanesulfonic anhydridearenesA sulfonic anhydride‐promoted direct trifluoromethylthiolation using NaSO2CF3 has been developed. The simple and practical strategy enabled the direct introduction of SCF3 moiety into unexplored arene scaffolds under r...
Tf2O‐Promoted Trifluoromethythiolation of Various Arenes Using NaSO2CF3Trifluoromethylthiolationsodium trifluoromethanesulfinatetrifluoromethanesulfonic anhydridearenesA sulfonic anhydride-promoted direct trifluoromethdoi:10.1002/adsc.201800702Liu JieZhao Xiaochun...
Trifluoromethylthiolationsodium trifluoromethanesulfinatetrifluoromethanesulfonic anhydridearenesA sulfonic anhydride-promoted direct trifluoromethylthiolation using NaSO2CF3 has been developed. The simple and practical strategy enabled the direct introduction of SCF3 moiety into unexplored arene scaffolds under r...
Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3sulfuration, sulfonation, S‐alkylationsulfoxides, sulfones, sulfenes and derivatives (benzene compoundsradical reactionshalogen compounds (benzene compounds...
S., Practical Method for the Cu- Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP), Org. Lett., 14, 4979-4981, 2012.Ye Y, Kunzi S, Sanford M. Practical method for the Cu-mediated trifluoromethylation of arylboronic...