self-assemblysupramolecular chemistryHighly selective, narcissistic self-sorting can be achieved in the formation of self-assembled cages of rare earth metals with multianionic salicylhydrazone ligands. The assembly process is highly sensitive to the length of the ligand and the coordination geometry. ...
Narcissistic self-sorting vs. statistic ligand shuffling within a series of phenothiazine-based coordination cages. 喜欢 0 阅读量: 29 作者:Marina,Frank,Lennard,Krause,Regine,Herbst-Irmer,Dietmar,Stalke,Guido,H 摘要: Previously, we introduced a series of anion-binding interpenetrated double-cages ...
Furthermore, the homogeneous interactions in biological systems also prompted scientists to urgently develop ligand motifs for self-recognition52,53. Fig. 1: The self-assembly of metallo-macrocycles by the narcissistic self-recognition tpy moieties. Two different self-sorting processes in coordination-...
The response to different wavelengths of light and the high specificity of the protein interactions allows for the independent self-assembly of each particle type with blue or red light and narcissistic selfsorting. Moreover, as both of the photoswitchable protein interactions are reversible in the ...
Narcissistic self-sorting of hydrogen-bonded dimeric capsules formed through self-assembly of flexible tripodal receptors in polar solventsSinghA.SunS. S.CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY
Narcissistic chiral self-sorting of molecular face-rotating polyhedradoi:10.1039/c7ob02727cXinchang WangPixian PengWei XuanYu WangYongbin ZhuangZhongqun TianXiaoyu CaoThe Royal Society of Chemistry
Narcissistic self-sorting vs. statistic ligand shuffling within a series of phenothiazine-based coordination cages 来自 Semantic Scholar 喜欢 0 阅读量: 33 作者:M Frank,L Krause,R Herbst-Irmer,D Stalke,GH Clever 摘要: Previously, we introduced a series of anion-binding interpenetrated double-...
Narcissistic, Integrative, and Kinetic Self-Sorting within a System of Coordination Cages Many useful principles of self-assembly have been elucidated through studies of systems where multiple components combine to create a single structure. More complex systems, where multiple product structures self-...
Only highly symmetrical cavitands are sorted out of a large number of potentially feasible products, which represents a rare example of intramolecular, narcissistic self-sorting. The reactivity order of the amine reactants and the changes in the Gibbs energies calculated using the semiempirical PM6 ...
Self-sortingBased on the chiral helicene-derived dipyridyl ligands, two pairs of chiral rhomboid metallacycles were constructed conveniently by the coordination-driven self-assembly. It was found that the chiral metallacycles showed a supramolecular depiction of the illusory Penrose stairs. Moreover,...