What is the name for PCL3? What are sulfide minerals? What is the compound name of Ba(NO3)2? What is carbonate's Lewis structure? What is the name of the covalent compound N2O5? What is the name of the acid whose formula is HI?
What is the compound name of Cu(NO3)2? What is the name of the compound CuCo3? What is the chemical name of (NH4)2Cr2O7? How many carbon atoms are in 2.12 mol of propane? What is the name of the covalent compound CCl4? Provide the IUPAC name for the compound. What else is pro...
The three-step route consisted of reactions of PCl3 with Grignard's reagent, sulphur and NaHS in turn in liquid phase. The title compound was purified through the formation of ammonium salt (o-CF3Ph)2PS2NH4 and characterized with NMR and HRMS. Both chemical and radiation stability of title ...
With a four-fold molar amount of KR* in benzene PCl3 gives the green diphosphanediide K2P2R*2 and the red phosphanediide K2PR*, and with an equimolar amount of ZnR*2 in heptane the compounds 1, 2, 4, 7 and 8 are obtained. The compound R*P=PR* (4), the first diphosphene ...
Silicaphosphite (silphos), [PCl3-n(SiO2)n], as a heterogeneous phosphorous compound, catalyzes the thiocyanation of benzylic alcohols and silyl and THP ethers in the presence of I2 and NH4SCN in refluxing CH3CN. The produced silphos oxide byproduct can be easily separated by a simple ...
In this series of, in part, novel phosphorus(III) compounds an intramolecular donor-acceptor interaction between NMe2 substituents and phosphorus has been observed which in the case of the product of the reaction of Me2NCH2CH2N(Me)SiMe3 with PCl3, led to a stable intramolecular complex, , ...
An annelated four-membered ring as structural unit of a polycyclic phosphane skeleton has been realized for the first time, namely in the title compound 1. The formation of the four-membered ring is enforced sterically. 1. a pale yellow solid, is formed in 25% yield from tBuPCl2,PCl3, ...
Reaction of B2Cl4 and PCl3 furnishes mainly the diphosphahexaborane P2(BCl)41, which, in accord with the Wade rules, is a closo compound with an octahedral structure.doi:10.1002/anie.198809251Prof.InstitutDr.InstitutWolfgangInstitutHaubold
Phosphorothionic triamide SP(NH2)3 is obtained by slow addition of SPCl3 dissolved in dry CH2Cl2 to a satured solution of NH3 in CH2Cl2 at —50°C. Ammonium chloride is removed from the resulting precipitate by treatment with HNEt2 followed by extraction with CH2Cl2. Coarse crystalline SP(...
Investigations of the reactivity of Cl- salts of the proposed cationic intermediates [Cl3P=N=PCl3]+ ([2]+) and [Cl3P=N-PCl2=N=PCl3]+ ([6]+) toward Ph3P=NSiMe3 (3a) provided evidence that under the usual polymerization conditions that involve a high monomer to initiator ratio, ...