The effect of different rare-earth chlorides (LaCl3,CeCl3,NdCl3 and SmCl3) and transition metal chlorides (MnCl2,NiCl2,CoCl2 and CuCl2) on the performances of the LTCFs reduction was discussed. The NaBH4/SmCl3 system was the best and the reduction rate reached 92% under optimum reaction conditions. Mechanism research sho...
ChemInform Abstract: Reduction of N-[-(4-Pyridyl)benzylidene]anisidine with NaBH4 in the Presence of NiCl2.pyridine derivativesreduction, hydrogenationChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ...
Efficient and selective reduction of α-pinene to cis-pinane by NaBH4 using NiCl26H2O/PEG-800/ethanol as the catalytic systemdoi:10.1080/00397911.2018.1560875Li, KaoxueWang, KangLiu, ChuanchaoYang, XuhaoChen, XiaRen, YangCao, Shuhua
NaBH4 in the presence of catalytic amounts of NiCl2路6H2O reduces a range of nitro compounds to their corresponding amines in high to excellent yields. Reduction reactions were carried out in H2O as green solvent within Immediate. 15 minutes. The method is simple, inexpensive, easily scaledup ...
NaBH4Ni nanoparticlesPEGsThe reduction of α-pinene by NaBH4 was achieved using NiCl2•6H2O in PEG-800/ethanol system under room temperature. Under the optimized conditions, the conversion of α-pinene and the selectivity of cis -pinane reached 97% and 98%, respectively. On the basis of ...
The reduction of α-pinene by NaBH4 was achieved using NiCl26H2O in PEG-800/ethanol system under room temperature. Under the optimized conditions, the conversion of α-pinene and the selectivity of cis-pinane reached 97% and 98%, respectively. On the basis of TEM and a series of ...
4. Mechanism of NaBH4 Regeneration Using NaBO2·xH2O as Raw Materials The above three works [77,79,80] are new discoveries for direct regeneration of NaBH4 from the hydrated NaBO2 with high yield. Some common points were found in their mechanism studies. In all of the three works, a ...