Electrical conductivity of Na1+xZr2SixP3?xO12Experimental/ ionic conduction in solidsphosphorus compoundssilicon compoundssodium compoundssolid solutionssuperionic conducting materialszirconium compounds/ Na 1+xZr 2Si xP 3-xO 12 (2.0lesxles2.4)
许希军1，林见烽1，罗雄伟1，赵经纬2，霍延平 摘要：本文综述了NASICON型Na1+xZr2SixP3-xO12固态电解质在钠金属电池领域的研究进展。重点介绍了该固态电解质的晶体结构、离子传导特性及其在提高电池安全性能方面的潜力。同时，探讨了其在钠金属电池中的应用前景与挑战。识别上方二维码或点击文末左下角“阅读原文”查看...
et al., “Compositional dependence of the electrochemical and structural parameters in the NASICON system (Na1+xSixZr2P3-xO12)”, Solid State Ionics, vol. 3/4, (1981), 215-128.Compositional dependence of the electrochemical and structural parameters in the Nasicon system (Nair. U. Von Alpen...
This paper gives a contribution to the crystallographic characterization of the Na1+xZr2SixP3‐xO12system, useful e.g. to analyze the right stoichiometric composition of a synthesized sample concerning this family of compounds, by powders X‐ray diffraction analysis. In the paper relations are in ...
Nakamura et al., Titanium Ion Substitution Ranges For Zirconium Ion in the Na1 xZr2SixP3 xO12 System , vol. 89, 1996, pp. 159 164, 1996, No Month.Osamu Nakamura,Yuria Saito,Mitsuhiro Kodama,Yoshifumi Yamamoto.Titanium ion substitution ranges for zirconium ion in the Na 1 + x Zr 2 Si...
1+xZr2SixP3-xO12 as Studied by 23Na Nutation NMR]]>Nutation NMRQuadrupole effectSuperionic conductorChemical exchange23Na two-dimensional nutation NMR was applied to Na1+x* Zr2SxP3-xO12 with x = 0, 1, and 2. The nutation spectrum in each compound consists of two clearly separated peak...
快离子导体钠NASICON型化合物通过高温固相反应合成了Na1+xZr2-yTiy,SixP3-xO12系统y=1,x=0-2.0的一系列合成物.其合成反应温度低于Zr-NASICON的合成温度.研究了系统的相变关系以及电导率,电导激活能与化学组成的关系.研究了系统合成物对水的稳定性.结果表明y=1.0,x=0.9的合成物的电导性能最好,对水的反应性也...
NASICONpyrolysis of organic solutionsphase compositionsolid electrolyteA new method for preparing Na1 + xZr2SixP3 – xO12 (0 < x < 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and ...
本文介绍钠快离子导体Na1+xZr(3-y)Tiy SixP3-xO12系统中x=2.0,y=0—2.0的一系列合成物的合成条件,相变关系及其两个单纯相—311相(相当于起始组成为Na3.0Zr1.0Ti1.0Si2.0P1.0O12.0和302相(相当于起始组成为Na3.0Ti2.0Si2.0P1.0O12.0的电导率和激活能. 室温时,311相和302相的电导率分别为0.78×10-4(Ω...
This paper gives a contribution to the crystallographic characterization of the Na1+xZr2SixP3-xO12 system, useful e.g. to analyze the right stoichiometric composition of a synthesized sample concerning this family of compounds, by powders X-ray diffraction analysis. In the paper relations are in ...