There is a strong intramolecular charge-assisted O–HO hydrogen bond in the non-planar hydrogen maleate anion. There are also two C–HO hydrogen bonds between the anion and cation. The cation makes a strong N–HO hydrogen bond to the anion, but also acts as a hyd...
A theoretical investigation of the N2O3- anion isomersNo dimer cationTrans-cis n2o3Dinitrogen trioxideVibrational-spectraPhotoelectron-spectrumSolid neonMatrixThe structures, binding energies and vibrational frequencies of various N2O3- structural isomers have been determined using the B3LYP and MP2 methods...
The Cu(II) cation is coordinated inside the N(7), N(13)-folded macrocycle. The coordination sphere of Cu(II) is a distorted square pyramid with N(7), O(10), N(13) of the macrocycle and O(1a) of the nitrate anion atoms occupying the corners of the base of the pyramid and the ...