Density functional calculationsLithiumNucleophilic substitutionN-Methylimidazole added to the strong organometallic Lewis acid B(C6F5)3 at the donor nitrogen atom to form the adduct 3 (characterized by X-ray diffraction). Deprotonation at the imidazole carbon atom C-2 was achieved by treatment wi...
Melting point -60 °C Boiling point 198 °C Density 1.03 g/mL at 25 °C Vapour pressure 0.4 mm Hg Flash(ing) point 198 °F PH 9.5-10.5 Proportion 1.031 Packaging and delivery Selling Units: Single item Single package size: 10X10X10 cm Single gross weight: 1.000 kg Show more ...
MW:82.1;Melting point:-60°C;Boiling point:198°C;Density:1.03 g/ml;Shelf life:12 months;HS code:29332990;Packaging:25 L/drum, 200 L/drum, 1000 L/IBC drum;Type:Syntheses Material Intermediates;Place of Origin:CN;CAS No.:616-47-7;Other Names:N-Methylimida
Synthesis, electrochemical studies, density functional analysis and X-ray structures of trans,cis,cis-[RuCl2(N-methylimidazole)2(SbPh3)2] and trans,cis,cis... The reaction of trans-[RuCl2(SbPh3)4] (1) (Ph=C6H5) (Inorg. Chim. Acta 208 (1993) 189) with tenfold excess N-...
Density functionalElectrochemistrytrans, cis, cis-[RuCl 2(L) 2(SbPh 3) 2] (L, Meim and Mepym) form by refluxing a mixture of trans-[RuCl 2(SbPh 3) 4] and L (1:10 molar ratio) in chloroform under anaerobic conditions. The two Meim ligands have a head-to-head arrangement at ...
DensityRegioselective formation of N-arylmethylimidazoles and C-arylimines was found in the reaction of 4,5-diamino-2,1,3-benzothiadiazole with selected aromatic aldehydes. The regiochemistry of the reaction products was confirmed by single crystal X-ray analysis. Gibbs free energy calculation using...
AcceptedManuscriptACombinedExperimentalandTheoreticalApproachtotheStudyofHydrogenBondInteractionintheBinaryMixtureofN-methylimidazolewithWaterR..
N-methylimidazole + methanolDensityViscosityRefractive indexVapor pressureTemperature-composition phase diagram•Density, viscosity, refractive index for mixture ofN-methylimidazole with methanol were measured at 308.15K.•Excess properties (VmE,∆η,∆n,∆G*E) for binary mixture were calculated....
Over the full molar fraction range, the density, viscosity, refractive index, conductivity and pH at the temperatures (298.15, 308.15, and 318.15)K, mixing enthalpy atT=298.15K, and1H-NMR were measured for the binary mixtures ofx N-methylimidazole (hereafter abbreviated toN-mim)+(1x) methanol...
At atmospheric pressure and over a full molar fraction range, for a binary mixture of x N-methylimidazole + (1-x) methanol, the density, viscosity and refractive index at 308.15 K were measured, and the Gibbs energy of activation of viscous flow was calculated. All these properties were, ...