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Redox Reaction between Main‐Group Elements (Te, Sn, Bi) and N‐Heterocyclic‐Carbene‐Derived Selenium Halides: A Facile Method for the Preparation of Monomeric Halides[J] . Sudesh T. Manjare,Sangeeta Yadav,Harkesh B. Singh,Ray J. Butcher.Eur. J. Inorg. Chem. . 2013 (30)...
百度试题 结果1 题目2. What is AG and E at 25℃ of a redox reaction for which n=1 and equilibrium constant K^θ=5*10^(3η) 相关知识点: 试题来源: 解析 2.-21100J⋅mol^(-1) ,0.219V 反馈 收藏
A new macrocyclic ligand, 1,3,5-triaza-2,4:7,8:,14,15-tribenzo-9,13-dioxacyclohexadeca-1,5-diene (L) was synthesized by reaction of 2,6-diaminopyridine and 1,3-bis(2-carboxyaldehyde phenoxy)propane. Then, its CuII, NiII, PbII, CoIII and LaIII complexes were synthesized by a ...
Understanding reversible anionic redox reactions is key to designing high-energy-density cathodes for lithium-ion batteries. Anionic redox activation in cation-disordered rock-salt Li1.17Ti0.58Ni0.25O2is shown to involve intermediate Ni3+/4+species that can evolve to Ni2+during relaxation. ...
The chemistry of precious-metal-based open-shell mononuclear complexes remains underdeveloped. Now it has been shown that iridium metalloradicals enable Ir(II)/Ir(IV) redox cycles and catalyse olefin isomerization more efficiently than their more commonly used closed-shell analogues, which typically ope...
Reaction with long-chain carbanions yield 1,1-diferrocenyl substituted n-alkanes, which are of potential interest as redox-responsive surfactants. Single crystal structure analyses reveal a tendency for ambiphilic behavior to increase with increasing chain length. Medium chain length 1,1-diferrocenyl-...
Generally, formation of the high-valent metal-oxo species is considered a key factor in catalyst activation for oxidation reactions, including WOR.36, 37, 38, 39, 40, 41, 42 Mechanistic observations and proposals are more diverse for different metal-oxide systems. Here, both water nucleophilic ...
induced IFN-β secretion and mRNA expression was not affected by myristic acid treatment (Fig.1b, c). In addition, myristic acid treatment decreased HSV-1-infection- and ISD-induced the expression of tumor necrosis factor-α (Tnfa), and interleukin-6 (Il6) (Fig.1d). Overall, these data...
factor15ε for the reduction of nitrite to N2is consistent across all experimental conditions (13.5‰ ± 3.7‰), suggesting it reflects the composition of the anammox bacteria community. Values of15ε for the oxidation of nitrite to nitrate (inverse isotope effect, − 16 to − 43...